n-i-p Type perovskite solar cell generally requires air oxidation of Spiro-OMeTAD layer to achieve high power conversion efficiency (PCE). However, the detailed oxidation mechanism is still not fully understood. In...
Despite the outstanding power conversion efficiency of triple-cation perovskite solar cells (PSCs), their low long-term stability in the air is still a major bottleneck for practical applications. The hygroscopic dopants...
Solution-processable
interlayers are important building blocks
for the commercialization of organic electronic devices such as organic
solar cells. Here, the potential of cross-linking to provide an insoluble,
stable, and versatile charge transport layer based on soluble organic
semiconductors is studied. For this purpose, a photoreactive tris-azide
cross-linker is synthesized. The capability of the small molecular
cross-linker is illustrated by applying it to a p-doped polymer used
as a hole transport layer in organic solar cells. High cross-linking
efficiency and excellent charge extraction properties of the cross-linked
doped hole transport layer are demonstrated. However, at high doping
levels in the interlayer, the solar cell efficiency is found to deteriorate.
Based on charge extraction measurements and numerical device simulations,
it is shown that this is due to diffusion of dopants into the active
layer of the solar cell. Thus, in the development of future cross-linker
materials, care must be taken to ensure that they immobilize not only
the host but also the dopants.
In this work, we measure the hole mobility in the model polymer system poly(3-hexylthiophene-2,5-diyl) by using different measurement techniques. Our main purpose is to determine how the recently developed charge extraction by a linearly increasing voltage technique for metal–insulator–metal devices (MIM-CELIV) compares to other commonly used methods, such as space charge limited currents and time-of-flight. Our findings suggest that the MIM-CELIV technique gives a slightly lower mobility than the other techniques, which is understandable given that the method measures the mobility of relaxed charge carriers in the dark unlike, for example, time-of-flight where charge carriers are photogenerated. In addition, we scrutinize the accuracy and reliability of the techniques used, showing that differences in mobility smaller than a factor of two are not detectable unless statistics from many devices are available.
The recently introduced perovskite solar cell (PSC) technology is a promising candidate for providing low-cost energy for future demands. However, one major concern with the technology can be traced back to morphological defects in the electron selective layer (ESL), which deteriorates the solar cell performance. Pinholes in the ESL may lead to an increased surface recombination rate for holes, if the perovskite absorber layer is in contact with the fluorine-doped tin oxide (FTO) substrate via the pinholes. In this work, we used sol-gel-derived mesoporous TiO2 thin films prepared by block co-polymer templating in combination with dip coating as a model system for investigating the effect of ESL pinholes on the photovoltaic performance of planar heterojunction PSCs. We studied TiO2 films with different porosities and film thicknesses, and observed that the induced pinholes only had a minor impact on the device performance. This suggests that having narrow pinholes with a diameter of about 10 nm in the ESL is in fact not detrimental for the device performance and can even, to some extent improve their performance. A probable reason for this is that the narrow pores in the ordered structure do not allow the perovskite crystals to form interconnected pathways to the underlying FTO substrate. However, for ultrathin (~20 nm) porous layers, an incomplete ESL surface coverage of the FTO layer will further deteriorate the device performance.
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