Controlling the morphology and surface passivation in perovskite solar cells is paramount in obtaining optimal optoelectronic properties. This study incorporates N-doped graphene nanosheets in the perovskite layer, which simultaneously induces an improved morphology and surface passivation at the perovskite/spiro interface, resulting in enhancement in all photovoltaic parameters.

Ionic liquids can retard the perovskite crystallization with the aim to form compact films with larger and more uniformly distributed grain size. The ionic liquid driven crystallization is exploited to prepared a record planar perovskite solar cell with stabilized power output of 19.5%.

Enhancing the stability of perovskite solar cells is crucial to the deployment of this technology. Carbon-based materials are promising candidates for providing long-term stable perovskite solar cells suitable for commercialization.