Chlorophylls are important antioxidants found in foods. We explored the mechanisms through which the a and b forms of chlorophyll and of pheophytin (the Mg-chelated form of chlorophyll) reduce oxidation: we used comet assay to measure prevention of H 2 O 2 DNA damage; we tested for quenching of 1,1-diphenyl-2-picrylhydrazyl (DPPH); we measured the ability to chelate Fe(II); and, we tested their ability to prevent formation of thiobarbituric acid reactive substances (TBARS) during Cu-mediated peroxidation of low density lipoprotein (LDL) in a chemical assay. All chlorophylls and pheophytins showed significant dose-dependent activity in the assays, with the pheophytins being the strongest antioxidants. Thus, these chemicals can prevent oxidative DNA damage and lipid peroxidation both by reducing reactive oxygen species, such as DPPH, and by chelation of metal ions, such as Fe(II), which can form reactive oxygen species.
The objectives of this study were to identify the antioxidants and antioxidant axtivity in 27 of Taiwan’s indigenous vegetables. Lycium chinense (Lc), Lactuca indica (Li), and Perilla ocymoides (Po) contained abundant quercetin (Que), while Artemisia lactiflora (Al) and Gynura bicolor (Gb) were rich in morin and kaempferol, respectively. Additionally, Nymphoides cristata (Nc) and Sechium edule (Se)-yellow had significantly higher levels of myricetin (Myr) than other tested samples. Cyanidin (Cyan) and malvidin (Mal) were abundant in Gb, Abelmoschus esculentus Moench (Abe), Po, Anisogonium esculentum (Retz.) Presl (Ane), Ipomoea batatas (Ib)-purple, and Hemerocallis fulva (Hf)-bright orange. Relatively high levels of Trolox equivalent antioxidant capacity (TEAC), oxygen radical absorption capacity (ORAC), and 1,1-diphenyl-2-picryl-hydrazyl (DPPH) radical scavenger were generated from extracts of Toona sinensis (Ts) and Po. Significant and positive correlations between antioxidant activity and polyphenols, anthocyanidins, Que, Myr, and morin were observed, indicating that these phytochemicals were some of the main components responsible for the antioxidant activity of tested plants. The much higher antioxidant activity of Po, Ts, and Ib (purple leaf) may be related to their higher Cyan, Que, and polyphenol content.
The “Santa Ana” wind is an offshore flow that affects Southern California periodically during the winter half of the year, typically between September and May. The winds can be locally gusty, particularly in the complex terrain of San Diego County, where the winds have characteristics of downslope windstorms. These winds can cause and/or rapidly spread wildfires, the threat of which is particularly acute during the autumn season before the onset of winter rains. San Diego’s largest fires, including the Cedar fire of 2003 and Witch Creek fire of 2007, occurred during Santa Ana wind events. A case study of downslope flow during a moderately intense Santa Ana event during mid-February 2013 is presented. Motivated by the need to forecast winds impinging on electrical lines, the authors make use of an exceptionally dense network of near-surface observations in San Diego County to calibrate and verify simulations made utilizing the Advanced Research version of the Weather Research and Forecasting (WRF) Model, which in turn is employed to augment the observations. Results demonstrate that this particular Santa Ana episode consists of two pulses separated by a protracted lull. During the first pulse, the downslope flow is characterized by a prominent hydraulic jumplike feature, while during the second one the flow possesses a clear temporal progression of winds downslope. WRF has skill in capturing the evolution and magnitude of the event at most locations, although most model configurations overpredict the observed sustained wind and the forecast bias is itself biased.
The authors survey a series of modeling studies that have examined the influences that cloud microphysical processes can have on tropical cyclone (TC) motion, the strength and breadth of the wind field, inner-core diabatic heating asymmetries, outer-core convective activity, and the characteristics of the TC anvil cloud. These characteristics are sensitive to the microphysical parameterization (MP) in large part owing to the cloud-radiative forcing (CRF), the interaction of hydrometeors with radiation. The most influential component of CRF is that due to absorption and emission of longwave radiation in the anvil, which via gentle lifting directly encourages the more extensive convective activity that then leads to a radial expansion of the TC wind field. On a curved Earth, the magnitude of the outer winds helps determine the speed and direction of TC motion via the beta drift. CRF also influences TC motion by determining how convective asymmetries develop in the TC inner core. Further improvements in TC forecasting may require improved understanding and representation of cloud-radiative processes in operational models, and more comprehensive comparisons with observations are clearly needed.
The “Santa Ana” winds of Southern California represent a high-impact weather event because their dry, fast winds can significantly elevate the wildfire threat. This high-resolution numerical study of six events of moderate or greater strength employs physics parameterization and stochastic perturbation ensembles to determine the optimal model configuration for predicting winds in San Diego County, with verification performed against observations from the San Diego Gas and Electric (SDG&E) mesonet. Results demonstrate model physics can have a material effect on the strength, location, and timing of the winds, with the land surface model playing an outsized role via its specification of surface roughness lengths. Even when bias in the network-averaged sustained wind forecasts is minimized, systematic biases remain in that many stations are consistently over- or underforecasted. The argument is made that this is an “unavoidable” error that represents localized anemometer exposure issues revealed through the station gust factor. A very simple gust parameterization is proposed for the mesonet based on the discovery that the network-averaged gust factor is independent of weather conditions and results in unbiased forecasts of gusts at individual stations and the mesonet as a whole. Combined with atmospheric humidity and fuel moisture information, gust forecasts can help in the assessment of wildfire risks.
Abiotic stresses affect crop plants and cause decreases in plant quality and productivity. Plants can overcome environmental stresses by activating molecular networks, including signal transduction, stress perception, metabolite production and expressions of specific stress-related genes. Recent research suggests that chemical priming is a promising field in crop stress management because plants can be primed by chemical agents to increase their tolerance to various environmental stresses. We present a concept to meet this objective and protect plants through priming of existing defense mechanisms avoiding manipulation of the genome. In addition, recent developments in plant molecular biology include the discovery of genes related to stress tolerance, including functional genes for protecting cells and regulatory genes for regulating stress responses. Therefore, enhancing abiotic stress tolerance using a transgenic approach to transfer these genes into plant genomes has attracted more investigations. Both chemical priming agents and genetic engineering can enhance regulatory and functional genes in plants and increase stress tolerance of plants. This review summarizes the latest findings of chemical priming agents and major achievements in molecular approaches that can potentially enhance the abiotic stress tolerance of plants.
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