Conductometric semiconducting metal oxide gas sensors have been widely used and investigated in the detection of gases. Investigations have indicated that the gas sensing process is strongly related to surface reactions, so one of the important parameters of gas sensors, the sensitivity of the metal oxide based materials, will change with the factors influencing the surface reactions, such as chemical components, surface-modification and microstructures of sensing layers, temperature and humidity. In this brief review, attention will be focused on changes of sensitivity of conductometric semiconducting metal oxide gas sensors due to the five factors mentioned above.

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Traditional ultra-dense wireless networks are recommended as a complement for cellular networks and are deployed in partial areas, such as hotspot and indoor scenarios. Based on the massive multiple-input multi-output (MIMO) antennas and the millimeter wave communication technologies, the 5G ultra-dense cellular network is proposed to deploy in overall cellular scenarios. Moreover, a distribution network architecture is presented for 5G ultra-dense cellular networks. Furthermore, the backhaul network capacity and the backhaul energy efficiency of ultra-dense cellular networks are investigated to answer an important question, i.e., how much densification can be deployed for 5G ultra-dense cellular networks. Simulation results reveal that there exist densification limits for 5G ultra-dense cellualr networks with backhaul network capacity and backhaul energy efficiency constraints.Submitted to IEEE Wireless Communications.

Cost-effective electrocatalysts based on nonprecious metals for efficient water splitting are crucial for various technological applications represented by fuel cell. Here, 3d transition metal layered double hydroxides (LDHs) with varied contents of Ni and Fe were successfully synthesized through a homogeneous precipitation. The exfoliated Ni-Fe LDH nanosheets were heteroassembled with graphene oxide (GO) as well as reduced graphene oxide (rGO) into superlattice-like hybrids, in which two kinds of oppositely charged nanosheets are stacked face-to-face in alternating sequence. Heterostructured composites of Ni2/3Fe1/3 LDH nanosheets and GO (Ni2/3Fe1/3-GO) exhibited an excellent oxygen evolution reaction (OER) efficiency with a small overpotential of about 0.23 V and Tafel slope of 42 mV/decade. The activity was further improved via the combination of Ni2/3Fe1/3 LDH nanosheets with more conductive rGO (Ni2/3Fe1/3-rGO) to achieve an overpotential as low as 0.21 V and Tafel plot of 40 mV/decade. The catalytic activity was enhanced with an increased Fe content in the bimetallic Ni-Fe system. Moreover, the composite catalysts were found to be effective for hydrogen evolution reaction. An electrolyzer cell powered by a single AA battery of 1.5 V was demonstrated by using the bifunctional catalysts.

The fifth generation (5G) wireless communication networks are being deployed worldwide from 2020 and more capabilities are in the process of being standardized, such as mass connectivity, ultra-reliability, and guaranteed low latency. However, 5G will not meet all requirements of the future in 2030 and beyond, and sixth generation (6G) wireless communication networks are expected to provide global coverage, enhanced spectral/energy/cost efficiency, better intelligence level and security, etc. To meet these requirements, 6G networks will rely on new enabling technologies, i.e., air interface and transmission technologies and novel network architecture, such as waveform design, multiple access, channel coding schemes, multi-antenna technologies, network slicing, cell-free architecture, and cloud/fog/edge computing. Our vision on 6G is that it will have four new paradigm shifts. First, to satisfy the requirement of global coverage, 6G will not be limited to terrestrial communication networks, which will need to be complemented with non-terrestrial networks such as satellite and unmanned aerial vehicle (UAV) communication networks, thus achieving a space-air-ground-sea integrated communication network. Second, all spectra will be fully explored to further increase data rates and connection density, including the sub-6 GHz, millimeter wave (mmWave), terahertz (THz), and optical frequency bands. Third, facing the big datasets generated by the use of extremely heterogeneous networks, diverse communication scenarios, large numbers of antennas, wide bandwidths, and new service requirements, 6G networks will enable a new range of smart applications with the aid of artificial intelligence (AI) and big data technologies. Fourth, network security will have to be strengthened when developing 6G networks. This article provides a comprehensive survey of recent advances and future trends in these four aspects. Clearly, 6G with additional technical requirements beyond those of 5G will enable faster and further communications to the extent that the boundary between physical and cyber worlds disappears.

Recent analysis by manufacturers and network operators has shown that current wireless networks are not very energy efficient, particularly the base stations by which terminals access services from the network. In response to this observation the Mobile Virtual Centre of Excellence (VCE) Green Radio project was established in 2009 to establish how significant energy savings may be obtained in future wireless systems. This article discusses the technical background to the project and discusses models of current energy consumption in base station devices. It also describes some of the most promising research directions in reducing the energy consumption of future base stations.

To get a real understanding on the complexity of origin and mechanism of visible emission for ZnO quantum dots (QDs), we systematically property of visible emission of ZnO QDs with tunable diameters in a range of 2.2−7.8 nm synthesized via a sol−gel route using self-made zinc−oleate complex as a precursor. It is indicated that the visible emission of ZnO QDs can be ascribed to singly ionized oxygen vacancies, which is associated with the paramagnetic centers with electron paramagnetic resonance (EPR) value of g = 2.0056. The visible emission property of the ZnO QDs displays highly size-dependent behavior. With ZnO QDs size decreasing, the visible emission peaks blue-shift to the positions with shorter wavelength due to quantum size effect, however, is different from that of band gap. Quantitative investigation shows that the visible emission can correspond to a transition of holes from the valence band to the preexisting deep donor energy level, which is different from the well-known conclusion that the visible emission is due to the transition of an electron from the conduction band to a deep trap. Two important points can be obtained: the defects of singly ionized oxygen vacancies determine the origin and intensity of visible emission of ZnO QDs; and the visible emission peak position of ZnO QDs is decided by their size, and a transition of holes from the valence band to the preexisting deep donor energy level is responsible for the visible emission of the ZnO QDs.

Coupling NiCoP bimetallic phosphide nanoparticles with alkali-induced 3D crinkled Ti3C2 effectively enhances the structural stability and improved reaction kinetics of anodes for SIBs.