Alkali-induced 3D crinkled porous Ti<sub>3</sub>C<sub>2</sub> MXene architectures coupled with NiCoP bimetallic phosphide nanoparticles as anodes for high-performance sodium-ion batteries

Zhao, Danyang; Zhao, Ruizheng; Dong, Shihua; Miao, Xianguang; Zhang, Zhiwei; Wang, Cheng-Xiang; Yin, Longwei

doi:10.1039/c9ee00308h

Cited by 336 publications

(234 citation statements)

References 49 publications

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“…To date, MXenes have triggered continuous breakthroughs in many areas, including MXene antennas, MXene pen, MXene membrane, supercapacitors, and rechargeable batteries, to name just a few. There are also several reviews covering chemical composition, synthesis routes, unique properties, electrochemical and photocatalysis, and various biomedical applications of MXene .…”

Section: Introductionmentioning

confidence: 99%

Two‐Dimensional Transition Metal Carbides and Nitrides (MXenes): Synthesis, Properties, and Electrochemical Energy Storage Applications

Zhang

et al. 2019

Energy & Environ Materials

391

181

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A family of 2D transition metal carbides and nitrides known as MXenes has received increasing attention since the discovery of Ti3C2 in 2011. To date, about 30 different MXenes with well‐defined structures and properties have been synthesized, and many more are theoretically predicted to exist. Due to the numerous assets including excellent mechanical properties, metallic conductivity, unique in‐plane anisotropic structure, tunable band gap, and so on, MXenes rapidly positioned themselves at the forefront of the 2D materials world and have found numerous promising applications. Particular interest is devoted to applications in electrochemical energy storage, whereby 2D MXenes work either as electrodes, additives, separators, or hosts. This review summarizes recent advances in the synthesis, fundamental properties and composites of MXene and highlights the state‐of‐the‐art electrochemical performance of MXene‐based electrodes/devices. The progresses in the field of supercapacitors and Li‐ion batteries, Li‐S batteries, Na‐ and other alkali metal ion batteries are reviewed, and current challenges and new opportunities for MXenes in this surging energy storage field are presented. In the focus of interest is the possibility to boost device‐level performance, particularly that of rechargeable batteries, which are of utmost importance in future energy technologies. Very recently, the 2019 Nobel Prize in Chemistry was awarded to the inventors of the Li‐ion battery. For sure, this will provide an additional stimulation to study fundamental aspects of electrochemical energy storage.

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Section: Introductionmentioning

confidence: 99%

Two‐Dimensional Transition Metal Carbides and Nitrides (MXenes): Synthesis, Properties, and Electrochemical Energy Storage Applications

Zhang

et al. 2019

Energy & Environ Materials

391

181

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“…MXenes possess high electrical conductivity and allow easy ion intercalation between layers, leading to excellent performance as electrodes for electrochemical capacitors (supercapacitors) [ 80 ] and various kinds of batteries [ 81–85 ] However, the present reports on printing MXenes for energy storage nearly all focus on supercapacitors, with few studies on the lithium‐ion battery.…”

Section: Printing Mxenes For Various Applicationsmentioning

confidence: 99%

MXene Printing and Patterned Coating for Device Applications

et al. 2020

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As a thriving member of the 2D nanomaterials family, MXenes, i.e., transition metal carbides, nitrides, and carbonitrides, exhibit outstanding electrochemical, electronic, optical, and mechanical properties. They have been exploited in many applications including energy storage, electronics, optoelectronics, biomedicine, sensors, and catalysis. Compared to other 2D materials, MXenes possess a unique set of properties such as high metallic conductivity, excellent dispersion quality, negative surface charge, and hydrophilicity, making them particularly suitable as inks for printing applications. Printing and pre/post-patterned coating methods represent a whole range of simple, economically efficient, versatile, and eco-friendly manufacturing techniques for devices based on MXenes. Moreover, printing can allow for complex 3D architectures and multifunctionality that are highly required in various applications. By means of printing and patterned coating, the performance and application range of MXenes can be dramatically increased through careful patterning in three dimensions; thus, printing/ coating is not only a device fabrication tool but also an enabling tool for new applications as well as for industrialization.devices. This is because solution processes such as liquid-phase exfoliation is crucial for the dispersion formation and mass production, as well as for the postsynthesis treatments on the 2D nanosheets such as sorting in terms of flake size and thickness, functionalization, compositing, etc., all of which are crucial for the ink formulation process required by printing. [6] Printed electronics technology has acquired considerable interest from both academia and industry recently. [7][8][9] Unlike traditional methods such as vacuum deposition and photolithography, printing technologies hold great promise for fast, high-volume, and low-cost manufacturing, especially for the fabrication of flexible devices. [10][11][12][13][14][15] The combination of 2D materials with printing started as early as 2012 when liquid-phase-exfoliated graphene dispersion was inkjet-printed to fabricate field-effect transistors. [16] It has since progressed from directly using the unoptimized dispersion obtained from the solution processing as inks to making formulated inks targeted toward specific printing methods and target applications (e.g., conductive tracks, transparent electrodes, transistors, photodetectors, energy storage devices such as supercapacitors, batteries, sensors, etc.). [17][18][19][20][21] As a new member to the 2D nanomaterials family, transition metal carbides, nitrides, and carbonitrides, also known as MXenes, possess outstanding electrochemical, electronic, optical, and mechanical properties, and thus have shown great promise in applications including energy storage, electronics, optoelectronics, biomedicine, sensors, and catalysis. [22][23][24][25] Research on MXenes dates back to 2011 when single-layered titanium carbide Ti 3 C 2 was synthesized and separated for the first time, [26] and has since evol...

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“…Interconnected architectures coupling conducting networks with enhanced physical entrapment of active materials are considered among the most promising candidates to promote the rate performance and energy density of LBs. [148,149] 3D carbon nanostructures such as carbon monolith, mesoporous carbon, porous carbon framework and corresponding nanocomposites owing to rich open space and exquisite hierarchical architectures, have enabled the development of LBs with higher energy density, lower cost, and stable performance. [150,151] It is demonstrated that the structural and interfacial design of 3D carbon nanostructures can not only establish favorable lithium reservoir but also enable lithium dendrite-free deposition.…”

Section: D Carbon Hierarchical Nanostructuresmentioning

confidence: 99%

Structure Design and Composition Engineering of Carbon‐Based Nanomaterials for Lithium Energy Storage

Geng

Peng

et al. 2020

Advanced Energy Materials

143

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Carbon‐based nanomaterials have significantly pushed the boundary of electrochemical performance of lithium‐based batteries (LBs) thanks to their excellent conductivity, high specific surface area, controllable morphology, and intrinsic stability. Complementary to these inherent properties, various synthetic techniques have been adopted to prepare carbon‐based nanomaterials with diverse structures and different dimensionalities including 1D nanotubes and nanorods, 2D nanosheets and films, and 3D hierarchical architectures, which have been extensively applied as high‐performance electrode materials for energy storage and conversion. The present review aims to outline the structural design and composition engineering of carbon‐based nanomaterials as high‐performance electrodes of LBs including lithium‐ion batteries, lithium–sulfur batteries, and lithium–oxygen batteries. This review mainly focuses on the boosting of electrochemical performance of LBs by rational dimensional design and porous tailoring of advanced carbon‐based nanomaterials. Particular attention is also paid to integrating active materials into the carbon‐based nanomaterials, and the structure–performance relationship is also systematically discussed. The developmental trends and critical challenges in related fields are summarized, which may inspire more ideas for the design of advanced carbon‐based nanostructures with superior properties.

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Alkali-induced 3D crinkled porous Ti₃C₂ MXene architectures coupled with NiCoP bimetallic phosphide nanoparticles as anodes for high-performance sodium-ion batteries

Abstract: Coupling NiCoP bimetallic phosphide nanoparticles with alkali-induced 3D crinkled Ti3C2 effectively enhances the structural stability and improved reaction kinetics of anodes for SIBs.

Cited by 336 publications

References 49 publications

Two‐Dimensional Transition Metal Carbides and Nitrides (MXenes): Synthesis, Properties, and Electrochemical Energy Storage Applications

Two‐Dimensional Transition Metal Carbides and Nitrides (MXenes): Synthesis, Properties, and Electrochemical Energy Storage Applications

MXene Printing and Patterned Coating for Device Applications

Structure Design and Composition Engineering of Carbon‐Based Nanomaterials for Lithium Energy Storage

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Alkali-induced 3D crinkled porous Ti3C2 MXene architectures coupled with NiCoP bimetallic phosphide nanoparticles as anodes for high-performance sodium-ion batteries

Abstract: Coupling NiCoP bimetallic phosphide nanoparticles with alkali-induced 3D crinkled Ti3C2 effectively enhances the structural stability and improved reaction kinetics of anodes for SIBs.

Cited by 336 publications

References 49 publications

Two‐Dimensional Transition Metal Carbides and Nitrides (MXenes): Synthesis, Properties, and Electrochemical Energy Storage Applications

Two‐Dimensional Transition Metal Carbides and Nitrides (MXenes): Synthesis, Properties, and Electrochemical Energy Storage Applications

MXene Printing and Patterned Coating for Device Applications

Structure Design and Composition Engineering of Carbon‐Based Nanomaterials for Lithium Energy Storage

Contact Info

Product

Resources

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Alkali-induced 3D crinkled porous Ti₃C₂ MXene architectures coupled with NiCoP bimetallic phosphide nanoparticles as anodes for high-performance sodium-ion batteries