The coordination chemistry towards the M(II) metal centre (M = Mn, Ni, Cu or Zn) of the hydrazone ligand (E)-2-amino-N'-[1-(pyridin-2-yl)ethylidene]benzohydrazide (H3L) has been explored and complexes having formulae [Mn(H2L)2] (1), {[Ni(H2L)2]. DMF. 0.4H2O} (2), {[Cu2(H2L)2(µ-Cl)2]. DMF} (3) and [Zn(H2L)2] (4) have been isolated and characterized by IR, UV-Visible spectroscopy, elemental analysis and Xray crystal diffraction. Structural studies reveal that the mononuclear complexes (1), (2) and (4) adopt highly distorted octahedral geometries while the dinuclear complex (3) adopts a square pyramidal geometry around each copper(II) ion.
In the title compound, [Ni(C9H9N4O2)2], the NiII ion is situated on a twofold rotation axis and is coordinated by two O and four N atoms from two tridentate {2-amino-2-oxo-N-[(1E)-1-(pyridin-2-yl-κN)ethylidene]acetohydrazidate ligands in a distorted octahedral geometry. In the crystal, N—H⋯O and N—H⋯N hydrogen bonds link the molecules into columns in [001]. The porous crystal packing is further stabilized via π–π interactions between the pyridine rings of neighbouring molecules [centroid–centroid distance = 3.746 (3) Å] with voids of 270 Å3.
Drilling techniques commonly used in Africa are rather well suited for areas where geologic formations are hard and groundwater is not located at higher depths. Thus, for a large number of people living in rural areas, access to improved drinking water sources is often limited, due to the high cost of drilled boreholes that is closely linked to geographical, geological and hydrogeological factors. The analysis of various contexts has revealed that, in order to improve access to safe drinking water for underserved communities and populations, it is possible to consider less costly alternative solutions, compared to current options for water supply which are still expensive. In this paper, a simplified drilling technology at a very low cost has been demonstrated: "the manual or hand drilling", which is a practical solution for less than 40-m deep water points in alluvial terrains or low resistance rock formations. The feasibility study of manual drilling in Senegal has revealed that, even if it is not practical in all geological formations of the country, manual drilling remains an alternative solution for reducing costs and improving accessibility to drinking water in several areas in Senegal, particularly in the Senegal River Valley, along the northern coast, in Fatick and Casamance coastal zones. This study was used to set up map of areas suitable for manual drilling boreholes; it aims to strengthen the local private sector capacity to meet growing drinking water needs in rural areas.
The deep and confined Maastrichtian aquifer contains considerable groundwater resources. It stretches over nearly 200,000 km2, from the northern part of Mauritania to the South of Guinea Bissau where it becomes shallow. The reservoir is composed mainly of coarse sands and sandstone interbedded with some clay units. The aquifer provides 40% of the total drinking water extracted from the different aquifers and nearly 800 wells equally distributed operate only in the top 50 m of the aquifer. Despite the importance of these resources for providing water in the rural and urban areas, the aquifer characteristics are not well defined. The present paper aims to define first the physical and chemical characteristics of the Maastrichtian aquifer. The reserve of the aquifer initially estimated at 350 billion m<sup>3</sup>, is reassessed using new data providing from cross sections realized as part of our research, through the Water Sectorial Project of the Ministry of Hydraulics. Data from oil wells and geophysical logging are used to investigate the geometry of the aquifer and the position of the fresh/salty water interface. The highest thickness of the aquifer is between 200 to 400 m and salty water is present below the fresh groundwater in the west side of the aquifer. In the Eastern side, potable water lies directly above the basement. The thickness of the aquifer increases from the west to the center, and then decreases towards the shallow basement rock in the South East. The average thickness is 250 m. Chemical data coming from pumping wells indicate high chloride (250 - 1600 mg/l) and fluoride content (1 - 5.5 mg/l). Therefore, the reassessment has to take into account the chemical aspect of the water
Gravel lateritic soils are intensively used in road geotechnical engineering. This material is largely representative of engineering soil all around the tropical African Countries [1,2]. Gravel lateritic soils from parts of Burkina Faso and Senegal (West Africa) are used to determine the evolution of the geotechnical parameters from one to ten cycles of modified Proctor compaction. This test procedure is non-common for geotechnical purposes and it was found suitable and finally adopted to describe how these problematic soils behave when submitted to a multi-cyclic set of Modified Proctor compactions (OPM) [3,4]. On another hand, we propose a correlation between the traffic and the cycles of compaction considered as the repeated load. From that, this work shows the generation of active fine particles, the decrease of the CBR index and also the mechanical characteristics (mainly the Young Modulus, E) that contribute at least to the main deformation of the road structure
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