In modern society, traffic and transportation and the manufacturing industry and construction industries continuously release large amounts of dust and particles into the atmosphere, which can cause heavy air pollution, leading to health hazards. The haze disaster, a serious problem in developing countries such as China and India, has become one of the main issues of global environmental pollution in recent decades. Many air filtration technologies have been developed. Air filtration using electrospun fibers that intercept fine particles/volatile organic gases/bacterium is a relatively new, but highly promising, technique. Due to their interconnected nanoscale pore structures, highly specific surface areas, fine diameters, and porous structure as well as their ability to incorporate active chemistry on a nanoscale surface, electrospun fibers are becoming a promising versatile platform for air filtration. In this review, following a short introduction concerning the need for air filtration and filtration theory and mechanism, electrospun nanofibers membranes for air filtration have been highlighted, including the preparation (electrospinning process) and the parameters relevant to filtration efficacy. Additionally, various types (function) of the electrospun air filtration membranes have been classified in detail. Furthermore, their potential in the filtration of fine particles and chemical pollutants has been discussed. Finally, the challenges of their practical application and the future prospects have been summarized. Given that some advanced electrospun air filtration nanofibrous membranes exist for treating different contaminants from various types of polluted atmosphere, it is believed that they should make a significant contribution in protection against air pollution.
Conducting polymer hydrogels (CPHs) have emerged as a fascinating class of smart soft matters important for various advanced applications. However, achieving the synergistic characteristics of conductivity, self-healing ability, biocompatibility, viscoelasticity, and high mechanical performance still remains a critical challenge. Here, we develop for the first time a type of multifunctional hybrid CPHs based on a viscoelastic polyvinyl alcohol (PVA)-borax (PB) gel matrix and nanostructured CNFs-PPy (cellulose nanofibers-polypyrrole) complexes that synergizes the biotemplate role of CNFs and the conductive nature of PPy. The CNF-PPy complexes are synthesized through in situ oxidative polymerization of pyrrole on the surface of CNF templates, which are further well-dispersed into the PB matrix to synthesize homogeneous CNF-PPy/PB hybrid hydrogels. The CNF-PPy complexes not only tangle with PVA chains though hydrogen bonds, but also form reversibly cross-linked complexes with borate ions. The multi-complexation between each component leads to the formation of a hierarchical three-dimensional network. The CNF-PPy/PB-3 hydrogel prepared by 2.0 wt % of PVA, 0.4 wt % of borax, and CNF-PPy complexes with a mass ratio of 3.75/1 exhibits the highest viscoelasticity and mechanical strength. Because of a combined reinforcing and conductive network inside the hydrogel, its maximum storage modulus (∼0.1 MPa) and nominal compression stress (∼22 MPa) are 60 and 2240 times higher than those of pure CNF/PB hydrogel, respectively. The CNF-PPy/PB-3 electrode with a conductivity of 3.65 ± 0.08 S m has a maximum specific capacitance of 236.9 F g, and its specific capacitance degradation is less than 14% after 1500 cycles. The CNF-PPy/PB hybrid hydrogels also demonstrate attractive characteristics, including high water content (∼94%), low density (∼1.2 g cm), excellent biocompatibility, plasticity, pH sensitivity, and rapid self-healing ability without additional external stimuli. Taken together, the combination of such unique properties endows the newly developed CPHs with potential applications in flexible bioelectronics and provides a practical platform to design multifunctional smart soft materials.
This article highlights the properties of stimuli-responsive bio-based polymeric systems and their main intelligent applications.
Interventions and policies for tackling air pollution issues exist and have been proven to be effective. Membrane materials of nanofibrous morphology are attractive for air filtration, and further alleviate the environmental issues. Electrospinning as a simple and versatile way to fabricate ultrafine fibers has been attracting tremendous attention. Herein, the recent researches and future trends of green electrospinning are expounded from the aspects of green degradable materials, green solution electrospinning, and solvent‐free electrospinning. The green degradable materials, including biomass materials, biosynthetic polymer materials, and chemical synthetic materials are reviewed. Following the concept of green electrospinning, electrospun polymer nanofibers via aqueous solution are discussed; additionally, further trends of solvent‐free electrospinning including melt‐electrospinning, anion‐curing electrospinning, UV‐curing electrospinning, thermo‐curing electrospinning, and supercritical CO2‐assisted electrospinning are highlighted. Furthermore, the applications of these electrospun nanofibrous membranes in the field of air filtration are discussed. In the end, the challenges of green electrospinning and future prospects are summarized. The development of green electrospinning is reviewed with an emphasis on current advanced solvent‐free research, where electrospun nanofibrous membranes are contributing to promising treatment strategies to solve environment issue.
Nylon-4,6 nanofibres with diameters ranging from about 1 µm down to 1 nm were prepared by electrospinning. The fibre diameter was varied by adjusting the concentration of the polymer solution. Electrospinning of a concentrated solution of as high as 20% nylon-4,6 by weight in formic acid produced a ribbon-like electrospun fibre with a ribbon width of about 850 nm. A semi-dilute concentration of 2% nylon-4,6 by weight produced the thinnest nylon-4,6 nanofibres with diameters of 1.6 nm or less. A small amount of pyridine was added to the electrospinning solution to avoid the formation of beaded nanofibres in the course of electrospinning at low concentrations. Scanning and transmission electron microscopy were used to characterize the size of the nanofibres. An ultra-thin nylon-4,6 nanofibre of 1.2 nm diameter might contain six or seven nylon-4,6 molecules in a typical cross-section of the fibre.
In this critical review, an overview is given on recent advances in the development and application of stimuliresponsive electrospun nanofibers.Please check this proof carefully. Our staff will not read it in detail after you have returned it. Translation errors between word-processor files and typesetting systems can occur so the whole proof needs to be read. Please pay particular attention to: tabulated material; equations; numerical data; figures and graphics; and references. If you have not already indicated the corresponding author(s) please mark their name(s) with an asterisk. Please e-mail a list of corrections or the PDF with electronic notes attached --do not change the text within the PDF file or send a revised manuscript.Please bear in mind that minor layout improvements, e.g. in line breaking, table widths and graphic placement, are routinely applied to the final version.Please note that, in the typefaces we use, an italic vee looks like this: n, and a Greek nu looks like this: n.We will publish articles on the web as soon as possible after receiving your corrections; no late corrections will be made.Please return your final corrections, where possible within 48 hours of receipt, by e-mail to: chemsocrev@rsc.org Reprints-Electronic (PDF) reprints will be provided free of charge to the corresponding author. Enquiries about purchasing paper reprints should be addressed via: http://www.rsc.org/publishing/journals/guidelines/paperreprints/. Costs for reprints are below: Stimuli-responsive electrospun nanofibers are gaining considerable attention as highly versatile tools which offer great potential in the biomedical field. In this critical review, an overview is given on recent advances made in the development and application of stimuli-responsive fibers. The specific features of these electrospun fibers are highlighted and discussed in view of the properties required for the diverse applications. Furthermore, several novel biomedical applications are discussed and the respective advantages and shortcomings inherent to stimuli-responsive electrospun fibers are addressed (136 references).
High‐strength polyimide mats have been formed from electrospun nanofibers of a rigid‐rod‐like poly(p‐phenylene biphenyltetracarboximide) (see Figure). Non‐woven mats of aligned nanofibers have a tensile strength of 664 MPa and a tensile modulus of 15.3 GPa. These high‐performance electrospun nanofibers with excellent mechanical properties and heat resistance are expected to be useful for applications such as protective clothing and heat‐resistant filters.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.