A novel ternary Ag3PO4/g-C3N4/hydroxyapatite photocatalyst was prepared, and its morphology, composition and structure were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, high-resolution transmission electron microscopy, and electron spin resonance, etc. The results show that g-C3N4 is evenly dispersed in the interior of hydroxyapatite, forming a homogeneous composite, and significantly improves the band gap structure of the material as a whole. Ag3PO4/g-C3N4/hydroxyapatite has good electron transfer ability and an appropriate energy band structure, which shows that the material has a good degradation effect and stability. Finally, based on the characterization and experimental results, a possible Z-scheme mechanism was proposed, and the active species involved in the reaction are mainly O2− and h+.

Traditional antimicrobial methods, such as antibiotics and disinfectants, may cause adverse effects, such as bacterial resistance and allergic reactions. Photocatalysts based on titanium dioxide (TiO2) have shown great potential in the field of antimicrobials because of their high efficiency, lack of pollution, and lack of side effects. This paper focuses on the antimicrobial activity of TiO2 under different light sources. To improve the photocatalytic efficiency of TiO2, we can reduce electron-hole recombination and extend the photocatalytic activity to the visible light region by doping with different ions or compounds and compounding with polymers. We can also improve the surface properties of materials, increase the contact area with microorganisms, and further enhance the resistance to microorganisms. In addition, we also reviewed their main synthesis methods, related mechanisms, and main application fields to provide new ideas for the enhancement of photocatalytic microorganism performance and application popularization in the future.