The enthalpy of mixing of binary In-Bi melts was measured by means of a calorimetric method at T = 1023, 875, 483 K. Its concentration dependence reveals a flat minimum in the region between the intermetallic phases InBi and In 2 Bi. The shape of the curve of the integral enthalpy of mixing for liquid In-Bi alloys is in agreement with the assumption of a competition between InBi-and In 2 Bi-like chemical ordering before solidification. Enthalpy of mixing / In-Bi molten alloys / Intermetallic phase / Associate
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