A key to the utilization of nitride-arsenides for long wavelength optoelectronic devices is obtaining low defect materials with long nonradiative lifetimes. Currently, these materials must be annealed to obtain device quality material. The likely defect responsible for the low luminescence efficiency is associated with excess nitrogen. Photoluminescence and capacitance–voltage measurements indicate the presence of a trap associated with excess nitrogen which decreases in concentration upon anneal. Our films are grown by elemental source molecular beam epitaxy and the background impurity concentration is low, thus we have investigated the role of crystalline defects. High resolution x-ray diffraction showed improved crystal quality after anneal. We observed that the lattice parameter does not decrease linearly with nitrogen concentration for levels of nitrogen above 2.9 mol % GaN. The fact that Vegard’s law is not observed, despite theoretical calculations that it should, indicates that nitrogen incorporates in locations other than the group V lattice sites. X-ray photoelectron spectroscopy revealed that nitrogen exists in two bonding configurations in not-annealed material: a Ga–N bond and another nitrogen complex in which N is less strongly bonded to gallium atoms. Annealing removes this second nitrogen complex. A combined nuclear reaction analysis and channeling technique showed that not annealed GaNAs contains a significant concentration of interstitial nitrogen that disappears upon anneal. We believe that this interstitial nitrogen is responsible for the deviation from Vegard’s law and the low luminescence efficiency of not annealed GaNAs and GaInNAs quantum wells.

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We report a surface-normal optically controlled optoelectronic modulator made from a reversed biased p-i (multiple quantum well)-n GaAs/AlGaAs structure with ultrathin barriers (5 Å) whose recovery time is based on diffusive conduction. Modulation of reflectivity from 0.3 to 0.6 and back again in about 50 ps was demonstrated using a 750 fJ control pulse at 855 nm. We also demonstrated modulated changes in power greater than the control pulse power—a type of signal gain—by a factor of 1.8-to-1. Strong changes in reflectivity combined with low required control power make this device potentially useful for high-speed switching arrays in such applications as time division demultiplexing.