The development of green flexible micro-supercapacitors (MSCs) is one of the biggest challenges in future wearable electronics. Flexible MSCs are mainly produced from non-biodegradable synthetic polymers, resulting in massive electronic waste. Moreover, complex multi-step fabrication increases their production cost. Here, the direct fabrication of highly conductive, intrinsically flexible, and green microelectrodes from naturally fallen leaves in ambient air using femtosecond laser pulses without any additional materials is reported. Hierarchically porous graphene is patterned on different types of leaves via a facile, mask-less, scalable, and one-step laser writing. Leaves consist of biominerals, which decompose into inorganic crystals that serve as nucleation sites for the growth of 3D mesoporous few-layer graphene. The femtosecond laserinduced graphene (FsLIG) microelectrodes formed on leaves have lower sheet resistance (23.3 Ω sq −1 ) than their synthetic polymer counterparts and exhibit an outstanding areal capacitance (34.68 mF cm −2 at 5 mV s −1 ) and capacitance retention (≈99% after 50 000 charge/discharge cycles). The FsLIG MSCs on a single leaf could easily power a light-emitting diode or a table clock and could be applied in wearable electronics, smart houses, and Internet of Things.
Mobile IPv6 (MIPv6) is a presentative protocol which supports global IP mobility. MIPv6 causes a long handover latency that a mobile node (MN) doesn't send or receive packets. This latency can be reduced by using Proxy Mobile IPv6 (PMIPv6). PMIPv6 is a protocol which network supports IP mobility without participation of the MN, and is studied in Network-based Localized Mobility Management (NETLMM) working group of IETF. There is much packet loss during handover in PMIPv6, although PMIPv6 reduces handover latency. In this paper, to reduce packet loss in PMIPv6 we propose Packet Lossless PMIPv6 (PL-PMIPv6) with authentication. In PL-PMIPv6 a previous mobile access gateway (pMAG) registers to a Local Mobility Anchor (LMA) on behalf of a new MAG (nMAG) during layer 2 handoff. Then, the nMAG buffers packets during handover after registration. Therefore, PL-PMIPv6 can reduce packet loss than them in MIPv6 and PMIPv6. Also, we use Authentication, Authorization and Accounting (AAA) infrastructure to authenticate the MN and to receive MN's profiles securely. We shows performance of PL-PMIPv6 through comparison of packet loss during handover of MIPv6, PMIPv6 and PL-PMIPv6.
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