This study aimed to assess the literature available on the effects, on peri-implant tissues, of degradation products released from dental implants as a consequence of therapeutic treatment for peri-implantitis and/or of wear-corrosion of titanium. A literature review of the PubMed medline database was performed up to December 31, 2016. The following search terms were used: "titanium wear and dental implant"; "titanium corrosion and dental implant"; "bio-tribocorrosion"; "peri-implantitis"; "treatment of periimplantitis"; "titanium particles release and dental implant"; and "titanium ion release and dental implant". The keywords were applied to the database in different combinations without limits of time period or type of work. In addition, the reference lists of relevant articles were searched for further studies. Seventy-nine relevant scientific articles on the topic were retrieved. The results showed that pro-inflammatory cytokines, infiltration of inflammatory response cells and activation of the osteoclasts activity are stimulated in peri-implant tissues in the presence of metal particles and ions. Moreover, degenerative changes were reported in macrophages and neutrophils that phagocytosed titanium microparticles, and mutations occurred in human cells cultured in medium containing titanium-based nanoparticles. Debris released from the degradation of dental implants has cytotoxic and genotoxic potential for peri-implant tissues. Thus, the amount and physicochemical properties of the degradation products determine the magnitude of the detrimental effect on peri-implant tissues. K E Y W O R D Sbio-tribocorrosion, debris, peri-implantitis, titanium ions, wear
Background: Zirconia has emerged as a versatile dental material due to its excellent aesthetic outcomes such as color and opacity, unique mechanical properties that can mimic the appearance of natural teeth and decrease peri-implant inflammatory reactions. Objective: The aim of this review was to critically explore the state of art of zirconia surface treatment to enhance its biological and osseointegration behavior in implant dentistry. Materials and Methods: An electronic search in PubMed database was carried out until May 2018 using the following combination of key words and MeSH terms without time periods: "zirconia surface treatment" or "zirconia surface modification" or "zirconia coating" and "osseointegration" or "biological properties" or "bioactivity" or "functionally graded properties". Results: Previous studies have reported the influence of zirconia-based implant surface on the adhesion, proliferation, and differentiation of osteoblast and fibroblasts at the implant to bone interface during the osseointegration process. A large number of physicochemical methods have been used to change the implant surfaces to improve the early and late bone-to-implant integration, namely: acid etching, gritblasting, laser treatment, UV light, CVD, and PVD. The development of coatings composed of silica, magnesium, graphene, dopamine, and bioactive molecules has been assessed although the development of a functionally graded material for implants has shown encouraging mechanical and biological behavior.
Two-piece implant systems are mainly used in oral implantology involving an osseointegrated implant connected to an abutment, which supports prosthetic structures. It is well documented that the presence of microgaps, biofilms and oral fluids at the implant-abutment connection can cause mechanical and biological complications. The aim of this review paper was to report the degradation at the implant-abutment connection by wear and corrosion processes taking place in the oral cavity. Most of the retrieved studies evaluated the wear and corrosion (tribocorrosion) of titanium-based materials used for implants and abutments in artificial saliva. Electrochemical and wear tests together with microscopic techniques were applied to validate the tribocorrosion behavior of the surfaces. A few studies inspected the wear on the inner surfaces of the implant connection as a result of fatigue or removal of abutments. The studies reported increased microgaps after fatigue tests. In addition, data suggest that micromovements occurring at the contacting surfaces can increase the wear of the inner surfaces of the connection. Biofilms and/or glycoproteins act as lubricants, although they can also amplify the corrosion of the surfaces. Consequently, loosening of the implant-abutment connection can take place during mastication. In addition, wear and corrosion debris such as ions and micro- and nanoparticles released into the surrounding tissues can stimulate peri-implant inflammation that can lead to pathologic bone resorption.
The aim of this study was to conduct a literature review on the potential benefits with the use of Morse taper dental implant connections associated with small diameter platform switching abutments. A Medline bibliographical search (from 1961 to 2014) was carried out. The following search items were explored: “Bone loss and platform switching,” “bone loss and implant-abutment joint,” “bone resorption and platform switching,” “bone resorption and implant-abutment joint,” “Morse taper and platform switching.” “Morse taper and implant-abutment joint,” Morse taper and bone resorption,” “crestal bone remodeling and implant-abutment joint,” “crestal bone remodeling and platform switching.” The selection criteria used for the article were: meta-analysis; randomized controlled trials; prospective cohort studies; as well as reviews written in English, Portuguese, or Spanish languages. Within the 287 studies identified, 81 relevant and recent studies were selected. Results indicated a reduced occurrence of peri-implantitis and bone loss at the abutment/implant level associated with Morse taper implants and a reduced-diameter platform switching abutment. Extrapolation of data from previous studies indicates that Morse taper connections associated with platform switching have shown less inflammation and possible bone loss with the peri-implant soft tissues. However, more long-term studies are needed to confirm these trends.
We present an analysis of the iron abundance in the hot gas surrounding galaxy groups and clusters. To do this, we first compile and homogenise a large dataset of 79 lowredshift (|z| = 0.03) systems (159 individual measurements) from the literature. Our analysis accounts for differences in aperture size, solar abundance, and cosmology, and scales all measurements using customised radial profiles for the temperature (T ), gas density (ρ gas ), and iron abundance (Z Fe ). We then compare this dataset to groups and clusters in the L-Galaxies galaxy evolution model.Our homogenised dataset reveals a tight T -Z Fe relation for clusters, with a scatter in Z Fe of only 0.10 dex and a slight negative gradient. After examining potential measurement biases, we conclude that at least some of this negative gradient has a physical origin. Our model suggests greater accretion of hydrogen in the hottest systems, via stripping of gas from infalling satellites, as a cause. At lower temperatures, L-Galaxies over-estimates Z Fe in groups, indicating that metal-rich gas removal (via e.g. AGN feedback) is required.L-Galaxies provides a reasonable match to the observed Z Fe in the intracluster medium (ICM) of the hottest clusters from at least z ∼ 1.3 to 0.3. This is achieved without needing to modify any of the galactic chemical evolution (GCE) model parameters. However, the Z Fe in intermediate-T clusters appears to be under-estimated in our model at z = 0. The merits and problems with modifying the GCE modelling to correct this are discussed.
Calcium carbonate is one of the most used raw materials in various industries, such as construction materials, food supplement, pharmaceutics, animal feed, plastic production, and others. Calcium carbonate can derive from marine wastes, like crustaceans and bivalve’s shells. The worldwide demand for new sources of food has increased exponentially, and following that tendency, the mariculture—especially the oyster culture—has been increasingly resorting to farming techniques. In 2016, 438 billion tons of oysters were produced. The majority of the shells were unduly discarded, presenting a public health problem. This article offers a solution based on the reuse and recycling of oyster shell residues in the production region of Florianópolis, SC, Brazil. The presented solution is an oyster shell by-product developed by a local company which produces artificial stone. The main component of the artificial stone is a composite material made of oyster shells incorporated in a polymeric resin. The mechanical properties, such as its flexural strength, hardness, Weibull modulus, and fracture analysis, were held in the artificial stone. The mechanical results of the new artificial stone were compared with other natural stones, such as granite and marble, and other commercial artificial stones. This material owns suitable mechanical properties for table tops and workbenches. Using this product as an artificial stone represents an innovation in the development of a new product and adds commercial value to local waste. This product is an excellent example of a circular economy for local producers who care about the environment, and it encourages the reduction of extraction of natural stone, such as granite and marble.
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