Zn metal anode has garnered growing scientific and industrial interest owing to its appropriate redox potential, low cost, and high safety. Nevertheless, the instability of Zn anode caused by dendrite formation, hydrogen evolution, and side reactions has greatly hampered its commercialization. Herein, an in situ grown ZnSe overlayer is crafted over one side of commercial Zn foil via chemical vapor deposition in a scalable manner, aiming to achieve optimized electrolyte/Zn interfaces with large‐scale viability. Impressively, thus‐derived ZnSe coating functions as a cultivator to guide oriented growth of Zn (002) plane at the infancy stage of stripping/plating cycles, thereby inhibiting the formation of Zn dendrites and the occurrence of side reactions. As a result, high cyclic stability (1530 h at 1.0 mA cm−2/1.0 mAh cm−2; 172 h at 30.0 mA cm−2/10.0 mAh cm−2) in symmetric cells is harvested. Meanwhile, when paired with V2O5 based cathode, assembled full cell achieves an outstanding capacity (194.5 mAh g−1) and elongated lifespan (a capacity retention of 84% after 1000 cycles) at 5.0 A g−1. The reversible Zn anode enabled by the interfacial manipulation strategy via ZnSe cultivator is anticipated to satisfy the demand of commercial use.
Separator modification has recently blossomed as an effective strategy to enable dendrite‐free Zn metal anodes. Nonetheless, the explored avenues are not conducive to mass production by far, and little attention is paid to the essence of separator regulation. Herein, a scalable Ti3C2Tx MXene‐decorated Janus separator is designed by spray‐printing MXene nanosheets over one side of commercial glass fibre (GF). The thus‐derived MXene‐GF separator affords abundant surface polar groups, good electrolyte wettability, and high ionic conductivity, which is beneficial to homogenizing local current distribution and promoting Zn nucleation kinetics. It is noted that MXene‐GF displays adjustable dielectric constants with an optimized value of 53.5, offering a directional electrical field to expedite Zn‐ion flux and repel anions. Accordingly, dendrite‐free Zn anode equipped within symmetric cells can be achieved with MXene‐GF, enabling a stable cycling for 1180 h at 1 mA cm−2 and 1200 h at 5 mA cm−2. More impressively, the assembled aqueous Zn‐ion battery full cell with Janus MXene‐GF separator realizes a favorable capacity retention ratio (77.9%) upon cycling for 1000 cycles at 5.0 A g−1. This strategy with scalability and effectiveness offers a new insight into high‐performance metal anodes.
Sodium (Na) metal batteries are nowadays appealing due to high specific capacity and low cost. However, major caveats including severe Na dendrite growth, unstable solid electrolyte interphase formation, and poor mechanical robustness have hampered its practicability. In this report, a highly sodiophilic and conductive host harnessing hierarchical vertical graphene (VG) cultivator and Co nanoparticle/N‐doped carbon decorator (Co‐VG/CC) is designed to accommodate Na metal throughout a facile infusion route. The strong interaction between Co‐VG/CC and Na is realized by sodiophilic Co nanoparticle/N‐doped carbon hybrid, resulting in excellent structural stability of the electrode. The well‐regulated Na adsorption behavior and uniform stripping/plating mechanism is systematically investigated via theoretical simulation in harmonization with in situ/ex situ electroanalytical analysis. In consequence, as‐derived Na@Co‐VG/CC electrode effectively inhibits the dendrite formation, resulting in promising electrochemical performances in symmetric cell configuration (functioning at an elevated rate of 5.0 mA cm−2 under 5.0 mAh cm−2 for 280 h, delivering a high capacity of 6.0 mAh cm−2 at 3.0 mA cm−2 for 1000 h and maintaining an ultralong lifespan up to 2000 h). Meanwhile, assembled flexible Na metal battery full cell can sustain to work for 120 h, representing a great advance in practical energy storage applications.
Flexible electromagnetic interference (EMI) shielding materials with ultrahigh shielding effectiveness (SE) are highly desirable for high‐speed electronic devices to attenuate radiated emissions. For hindering interference of their internal or external EMI fields, however, a metallic enclosure suffers from relatively low SE, band‐limited anti‐EMI responses, poor corrosion resistance, and non‐adaptability to the complex geometry of a given circuit. Here, a broadband, strong EMI shielding response fabric is demonstrated based on a highly structured ferromagnetic graphene quartz fiber (FGQF) via a modulation‐doped chemical vapor deposition (CVD) growth process. The precise control of the graphitic N‐doping configuration endows graphene coatings on specifically designable quartz fabric weave with both high conductivity (3906 S cm−1) and high magnetic responsiveness (a saturation magnetization of ≈0.14 emu g−1 under 300 K), thus attaining synergistic effect of EMI shielding and electromagnetic wave (EMW) absorption for broadband anti‐EMI technology. The large‐scale durable FGQF exhibits extraordinary EMI SE of ≈107 dB over a broadband frequency (1–18 GHz), by configuring ≈20 nm‐thick graphene coatings on a millimeter‐thick quartz fabric. This work enables the potential for development of an industrial‐scale, flexible, lightweight, durable, and ultra‐broadband strong shielding material in advanced applications of flexible anti‐electronic reconnaissance, antiradiation, and stealthy technologies.
The direct synthesis of low sheet resistance graphene on glass can promote the applications of such intriguing hybrid materials in transparent electronics and energy-related fields. Chemical doping is efficient for tailoring the carrier concentration and the electronic properties of graphene that previously derived from metal substrates. Herein, we report the direct synthesis of 5 in. uniform nitrogen-doped (N-doped) graphene on the quartz glass through a designed low-pressure chemical vapor deposition (LPCVD) route. Ethanol and methylamine were selected respectively as precursor and dopant for acquiring predominantly graphitic-N-doped graphene. We reveal that by a precise control of growth temperature and thus the doping level the sheet resistance of graphene on glass can be as low as one-half that of nondoped graphene, accompanied by relative high crystal quality and transparency. Significantly, we demonstrate that this scalable, 5 in. uniform N-doped graphene glass can serve as excellent electrode materials for fabricating high performance electrochromic smart windows, featured with a much simplified device structure. This work should pave ways for the direct synthesis and application of the new type graphene-based hybrid material.
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