Ti1−xCoxO2 polycrystalline films have been prepared on Si(0 0 1) substrates by the plasma enhanced chemical vapour deposition technique at 280 °C without using any carrier gas. All the films show room-temperature ferromagnetic behaviours and no ferromagnetic clusters are detected by x-ray diffraction, x-ray photoelectron spectroscopy, atomic force microscopy, Raman and superconducting quantum interference device measurements as the doping concentration is lower than 4%. In addition, the formation of non-ferromagnetic CoTiO3 under heavy doping is considered to be responsible for the degradation of magnetization in Ti1−xCoxO2 polycrystalline films. Furthermore, saturated magnetization of Ti1−xCoxO2 films is found to decrease with the increasing duration of oxygen-plasma processing, indicating that the oxygen vacancies in the films play an important role in the generation of ferromagnetic Ti1−xCoxO2 films.
High density ZnO nanostructures were fabricated on Au coated Si and quartz substrates through once and the same oxidative evaporation of pure zinc powder. The coated side of the substrate was intentionally positioned in two directions of face and back to the zinc sources. Structure, morphology and optical properties of the samples were investigated by scanning electron microscopy, X-ray diffraction, Raman spectra and room temperature photoluminescence measurements. The results showed that the samples on the different substrates with different directions have three different morphologies, including film-, rod- and comb-like nanostructures. Photoluminescence spectra of the samples showed the various bands centered in UV (380-390 nm), blue (470-490 nm), green (500-550 nm) and orange (610-620 nm) region. It demonstrates that the substrate material and the direction of substrate significantly affect the growth of ZnO nanostructures.
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