Herbicides applied in cropping in the Great Barrier Reef catchment in Queensland, pose a threat to water quality in riverine environments and the reef lagoon. With the introduction of ReefPlan in 2009, which sets a target of a 50% reduction in herbicides entering the Great Barrier Reef lagoon by 2013, there is a need to investigate water quality implications of weed management practices. Models are the most logical approach to extrapolate from the relatively small experimental database to a wider range of conditions and also investigate the impact of management options. Towards this end, a pesticide module has been added to the HowLeaky crop and soil water balance model. This pesticide module is based on algorithms from GLEAMS. An extraction coefficient to predict concentrations of chemicals in runoff as a function of soil concentrations is a central concept. Good agreement has been found between model predictions and measured data for pesticide runoff from experimental field sites. Sensitivity analysis shows major factors affecting transport potential are the application rate and degradation rate of the pesticide. Using modelled simulations, the water quality impacts of weed management practices incorporating a heavy reliance on residual herbicides (atrazine, diuron) in grains farming have been explored and compared to the use of knockdowns herbicides (e.g. 2,4-D, glyphosate). Several pesticides that are being increasingly used in the grains and cane industry in Queensland are also assessed (e.g. isoxaflutole, s-metolachlor, pendimethalin). Simulation results demonstrate that reducing the use of residuals in favour of knockdown herbicides would result in an improvement in runoff water quality. However, caution is needed when selecting 'emerging' pesticides to replace the traditionally applied residuals, as use of these products may not lead to improved water quality. The examples presented demonstrate the utility of the HowLeaky pesticides module for exploring runoff water quality implications from weed management practice options in cropping lands.
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