Oxygen vacancy (OV) controlled TiO2 nanotubes, having diameters of 50–70 nm and lengths of 200–250 nm, were synthesized by electrochemical anodization in the mixed electrolyte comprising NH4F and ethylene glycol with selective H2O content. The structural evolution of TiO2 nanoforms has been studied by field emission scanning electron microscopy. Variation in the formation of OVs with the variation of the structure of TiO2 nanoforms has been evaluated by photoluminescence and X-ray photoelectron spectroscopy. The sensor characteristics were correlated to the variation of the amount of induced OVs in the nanotubes. The efficient room temperature sensing achieved by the control of OVs of TiO2 nanotube array has paved the way for developing fast responding alcohol sensor with corresponding response magnitude of 60.2%, 45.3%, and 36.5% towards methanol, ethanol, and 2-propanol, respectively.
Micro/Nano sensors based on oxide semiconductors received worldwide much interest due to their remarkable electrical conductivity and better stability, wide range of dimensional structures, large scale production and cost effective....
The present study concerns development of an efficient alcohol sensor by controlling the stoichiometry, length, and wall thickness of electrochemically grown TiO2 nanotube array for its use as the sensing layer. Judicious variation of H2O content (0, 2, 10 and 100% by volume) in the mixed electrolyte comprising ethylene glycol and NH4F resulted into the desired variation of stoichiometry. The sensor study was performed within the temperature range of 27 to 250 °C for detecting the alcohols in the concentration range of 10-1000 ppm. The nanotubes grown with the electrolyte containing 2 vol % H2O offered the maximum response magnitude. For this stoichiometry, variation of corresponding length (1.25-2.4 μm) and wall thickness (19.8-9 nm) of the nanotubes was achieved by varying the anodization time (4-16 h) and temperatures (42-87 °C), respectively. While the variation of length influenced the sensing parameters insignificantly, the best response magnitude was achieved for ∼13 nm wall thickness. The underlying sensing mechanism was correlated with the experimental findings on the basis of structural parameters of the nanotubes.
Highly stable, low temperature (27–175 °C) alcohol (ethanol, methanol and 2-propanol) sensing performance of a hydrothermally grown tetragonal TiO2nanorod array, targeting the detection level of 1–100 ppm, is reported in this paper.
In this paper, we report on the development of a highly sensitive, relatively low-temperature ethanol sensor based on sol-gel derived p-TiO 2 thin film. The p-type anatase TiO 2 thin film was deposited by sol-gel technique on a thermally oxidized <100> p-Si (resistivity 5 cm) substrate. Anatase TiO 2 phase with <101> nanocrystallinity was confirmed with an average particle size of ∼11 nm from X-ray diffraction and field emission scanning electron microscopic study. Ethanol sensor study, in the resistive mode, was carried out at a relatively low operating temperature range (75°C-175°C) for sensing low concentrations of ethanol in air (5-100 ppm). Response magnitude of ∼146% was observed at 150°C toward 100-ppm ethanol (in air) with corresponding response time and recovery time of 39 and 15 s, respectively. The sensor showed appreciably highresponse magnitude (129%) even at low ethanol concentration (5 ppm) with acceptable response and recovery time (54 and 22 s, respectively) at the same operating temperature (150°C). At a particular temperature, for all the ethanol concentrations, sensor showed minimal base line resistance drift, thereby offering highly repeatable and stable sensing performance. Ethanol selectivity study against other volatile organic compounds, such as methanol, acetone, and 2-butanone, was also investigated and was found to be quite promising. Ethanol sensing mechanism for such p-type TiO 2 has also been discussed in the light of corresponding oxygen vacancy model. Index Terms-p-TiO 2 , ethanol sensing, high response, relatively low operating temperature, low concentrations, repeatibility, selectivity.
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