Table A3. Bond lengths [A] and angles [ 0 for [Co(3-Cl-acacen)(NH3)2]BPh4. Co-O (1) #1 Co-N(1) #1#1 C(S)-H(SA) C(S)-H(5C) C(6)-H(6B) C(20)-C(21) C(20)-B C(21)-H(21) C(22)-H(22) C(23)-H(23) C(24)-H(24) C(40)-C(41)#1 C(40)-B C(41)-H(41) C(42)-H(43) C(43) -H(43) C(30)-C(31) C(31)-C(32) C(32)-C(33) C(33) -C(32)#1 C(5)-H(5B) 0.96 C(6)-H(6A) 0.96 C(6)-H(6C) 0.96 C(20)-C(25) 1.407(8) C(21)-C(22) 1.381(9) C(22)-C(23) 1.362(10) C(23)-C(24) 1.364(10) C(24)-C(25) 1.409(9) C(25)-H(25) 0.93 C(40)-C(41) 1.395(7) C(41)-C(42) 1.392(9) C(42)-C(43) 1.373(8) C(43)-C(42)#1 1.373(8) C(30)-C(31)#1 1.389(7) C(30)-B 1.629(13) C(31)-H(31) 0.93 C(32)-H(32) 0.93 C(33)-H(33) 0.93 0(1)#1-Co-N(1)#1 94.06(14) O(1)#1-Co-N(1)178.4(2) N(1)#1-Co-N(1) 87.58(5)87.5(2) N(1)#1-Co-N(2) 92.3(2) N(1B)-Co-N(2) 92.3(2) O(1)#1-Co-N(3) 89.3(2) N(1)#1-Co-N(3) 90.74(14) N(1B)-Co-N(3) 90.74(14) N(2)-Co-N(3) 175.8(3) N(1B)#1-N(1)-C(4) 107.767(5) N(1B)#1-N(1)-C(4B)#1 121.179(8) C(4)-N(1)-C(4B)#1 26.576(11) C(3)-N(1)-Co 126.8(4) C(4B)#1-N(1)-Co 104.54(3) N(1)#1-N(1B)-C(4)#1 72.232(5) N(1)#l-N(1B)-C(4B) 58.820(8)

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