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The adsorptive removal of total dissolved solids by activated coal using response surface methodology was investigated. A four-variable central composite experimental design was applied to correlate the adsorption variables (effluent pH, adsorbent dosage, contact time, and adsorption temperature). The adsorption variables were optimized based on the removal of total dissolved solids from fibre cement industry effluent. Three-dimensional surface plots were generated to estimate the effect of the combinations of the independent variables on the adsorption efficiency. The results of the model validation gave experimental yield 96.2%, predicted yield 96.5% obtained at effluent pH 6.27, adsorbent dosage 27.60 mg L −1 , contact time 48.00 min, and adsorption temperature of 31.00 °C. The good agreement found between observed and predicted values supports the suitability of the applied model to predict the adsorption treatment.

Notwithstanding the increased toxic heavy metals/metalloids (THMs) accumulation in (edible) organs owed to goat′s feeding habit and anthropogenic activities, the chevon remains increasingly relished as a special delicacy in Nigeria. Specific to the South-Eastern region, however, there is paucity of relevant data regarding the prevalence of THMs in goat carcasses processed for human consumption. This work was, therefore, aimed to investigate the detection, distribution and health risk assessment of THMs in goat carcass processed for human consumption in South-Eastern Nigeria. To achieve this, a total of 450 meat samples (kidney, liver and muscle) were evaluated from 150 randomly selected goat carcasses processed in two major slaughterhouses in Enugu State. The detection, distribution, as well as health risk assessment parameters followed standard procedures. Results revealed that at least one THM was detected in 56% of the carcasses. Mean concentrations of arsenic (As) were 0.53 ± 0.10 mg/kg, 0.57 ± 0.09 mg/kg and 0.45 ± 0.08 mg/kg, lead (Pb) were 0.48 ± 0.38 mg/kg, 0.45 ± 0.24 mg/kg and 0.82 ± 0.39 mg/kg, cadmium (Cd) was 0.06 ± 0.32 mg/kg, 0.02 ± 0.00 mg/kg, and 0.02 ± 0.00 mg/kg for kidney, liver and muscle tissues, respectively. The estimated daily intakes (EDI) for all THMs were above the recommended safe limits. The target hazard quotient (THQ) and hazard index (HI) computed for all As, Cd and Pb fell below unity in all the studied organs, which indicated no non-carcinogenic risks. Curtailing the anthropogenic activities that aid the THM-contamination in goat production/processing lines is recommended. Screening for THM-contamination in Nigerian slaughterhouses is imperative, so as to ascertain the toxicological safety of meats intended for human consumption.

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The health risk of students’ exposure to some potentially toxic metals in classroom dusts in Southeast, Nigeria was assessed. Dust particles were collected from classrooms in some public high schools and digested with aqua regia before analysis for selected metals by atomic absorption spectrophotometry. The geoaccumulation index, contamination factor and the pollution load index were assessed from the metal concentrations of the dust. Hazard quotient and cancer risk index were used to estimate the potential health risk of students’ exposure to the metals in the dust. The metal concentrations (mg/kg) were in the ranges of 1.57–175.38 (Cr); 0.93–463.28 (Cu); 31.94.76–6623.41 (Fe); 4.96–143.98 (Ni); 2.64–375.27 (Zn); and 2.35–53.96 (Pb).The geo-accumulation index values showed that all the dust samples were polluted with Fe and Cr; and unpolluted with other metals with few exemptions. The contamination factor values showed that all the schools but one had a low contamination status due to Ni and Cu. There was moderate contamination by Pb at all the schools but two. All the schools had high contamination of Cr and Fe. The pollution load index indicated that the quality of all the classrooms was deteriorated. The calculated values of hazard quotient indicated that ingestion of dust at most of the classrooms would have no significant risk of non-carcinogenic effects on the health of the students. Dermal contact with the dust at all the classrooms would expose students to adverse effects of Fe. There will be adverse effect due to Pb for dermal contact with dust at most of the schools. Ingestion of dust particles at classrooms in all the schools would have carcinogenic effect due to Ni. Correlation analysis indicated that the sources of the metals varied. This study provided baseline data for relevant bodies to use in monitoring and controlling pollution so as to protect students from toxic metals.