Biochar, like most other adsorbents, is a carbonaceous material, which is formed from the combustion of plant materials, in low-zero oxygen conditions and results in a material, which has the capacity to sorb chemicals onto its surfaces. Currently, research is being carried out to investigate the relevance of biochar in improving the soil ecosystem, digestate quality and most recently the anaerobic digestion process. Anaerobic digestion (AD) of organic substrates provides both a sustainable source of energy and a digestate with the potential to enhance plant growth and soil health. In order to ensure that these benefits are realised, the anaerobic digestion system must be optimized for process stability and high nutrient retention capacity in the digestate produced. Substrate-induced inhibition is a major issue, which can disrupt the stable functioning of the AD system reducing microbial breakdown of the organic waste and formation of methane, which in turn reduces energy output. Likewise, the spreading of digestate on land can often result in nutrient loss, surface runoff and leaching. This review will examine substrate inhibition and their impact on anaerobic digestion, nutrient leaching and their environmental implications, the properties and functionality of biochar material in counteracting these challenges.
Physicochemical properties ofCucurbita pepo, Brachystegia eurycoma, Cucumis melo, Luffa cylindrica, andArachis hypogaeaoils were studied to determine their potential as viable feedstock for biodiesel production. The nonedible oils were extracted by solvent extraction using n-hexane while the oil ofArachis hypogaeawas procured. All the oils were characterized for specific gravity, pH, ash content, iodine value, acid value, saponification value, peroxide value, free fatty acid, flash point, kinematic viscosity, and refractive indices using standard methods.Cucurbita peposeeds had very high oil content when compared to the others. Specific gravity and flash point of the oils were satisfactory. However, moisture content of some of the oils exceeded the stipulated ASTM standard for biodiesel production. Again, acid values of the nonedible oils were very high and exceeded the ASTM standard. They also exceeded the acid value ofArachis hypogaeaoil except forLuffa cylindricaoil. Results indicate that the oils are potential biodiesel feedstocks. However, overall results indicate that the nonedible oils are not suitable for single-stage transesterification process to biodiesel but would be better suited for the two stage esterification and subsequent transesterification in order to obtain reasonable yields of the methyl esters.
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