Experimental density, viscosity, speed of sound, and refractive index for binary mixtures of N-methyl-2-pyrrolidone with water, ethanol, and ethanolamine were measured over the entire composition range at different temperatures of (293.15 to 323.15) K. The effect of composition and temperature upon different physical properties has been analyzed. Excess volumes have been calculated, and their dependence on composition was mathematically represented by a Redlich−Kister-type equation.
The present work analyzes and compares the carbon dioxide absorption process in aqueous solutions of different amines (MEA, monoethanolamine; DEA, diethanolamine; TEA, triethanolamine). This study evaluates the influence of the reagents nature upon absorption using a semicontinuous regime in a bubble contactor. 13 C and 1 H nuclear magnetic resonance (NMR) spectroscopy has been used to analyze species (reagents and/or products) in the reaction medium. In this way, the influence of the amino group substitution degree and carbon dioxide loading upon the chemical absorption mechanism were analyzed.
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