2011
DOI: 10.1021/je100967k
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Density, Speed of Sound, Viscosity, Refractive Index, and Excess Volume ofN-Methyl-2-pyrrolidone + Ethanol (or Water or Ethanolamine) fromT= (293.15 to 323.15) K

Abstract: Experimental density, viscosity, speed of sound, and refractive index for binary mixtures of N-methyl-2-pyrrolidone with water, ethanol, and ethanolamine were measured over the entire composition range at different temperatures of (293.15 to 323.15) K. The effect of composition and temperature upon different physical properties has been analyzed. Excess volumes have been calculated, and their dependence on composition was mathematically represented by a Redlich−Kister-type equation.

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Cited by 116 publications
(53 citation statements)
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“…[2] Glycerol and N-methyl-2-pyrrolidone were added to water for enhancing the solubility of low water-soluble pharmaceuticals and also used as their individual or mixtures for various purposes. [3][4][5][6][7][8][9][10][11] The viscosity and/or surface tension of glycerol [12][13][14][15][16][17][18][19][20][21][22][23][24][25][26][27] and N-methyl-2-pyrrolidone [28][29][30][31][32][33] have been reported in the literature. To the best of our knowledge, there is no report on the properties of glycerol + N-methyl-2-pyrrolidone mixtures in the literature.…”
Section: Introductionmentioning
confidence: 99%
“…[2] Glycerol and N-methyl-2-pyrrolidone were added to water for enhancing the solubility of low water-soluble pharmaceuticals and also used as their individual or mixtures for various purposes. [3][4][5][6][7][8][9][10][11] The viscosity and/or surface tension of glycerol [12][13][14][15][16][17][18][19][20][21][22][23][24][25][26][27] and N-methyl-2-pyrrolidone [28][29][30][31][32][33] have been reported in the literature. To the best of our knowledge, there is no report on the properties of glycerol + N-methyl-2-pyrrolidone mixtures in the literature.…”
Section: Introductionmentioning
confidence: 99%
“…An increase in HMTA concentration causes a decrease in the effect of temperature on experimental data until the same value is reached at an HMTA molar fraction close to 0.08. This behavior has been observed only for some amines in aqueous solutions related with the formation of rigid structures and especially clathrates for this type of aqueous solution …”
Section: Resultsmentioning
confidence: 97%
“…64,65 The solid line depicts regressed results. 2), w 1 = 0.1000 (▲), 65 w 1 = 0.2000 (▷); 64,65 MEA (1) + NMP (2), w 1 = 0.2089 ( ◇ ), 66 w 1 ≈ 0.30 (×). 66,67 experimental data are presented in Figures 3, 4, and 5 and listed in Tables 10 and 11.…”
Section: Resultsmentioning
confidence: 99%
“…2), w 1 = 0.1000 (▲), 65 w 1 = 0.2000 (▷); 64,65 MEA (1) + NMP (2), w 1 = 0.2089 ( ◇ ), 66 w 1 ≈ 0.30 (×). 66,67 experimental data are presented in Figures 3, 4, and 5 and listed in Tables 10 and 11. The fitted parameters and statistical deviations are listed in Tables 12 and 13.…”
Section: Resultsmentioning
confidence: 99%
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