The demand of new materials and processes for nanofiber fabrication to enhance the performance of air filters is steadily increasing. Typical approaches to obtain nanofibers are based on top-down processes such as melt blowing, centrifugal spinning, and electrospinning of polymer materials. However, fabrication of polymer nanofibers is limited with respect to either a sufficiently high throughput or the smallest achievable fiber diameter. This study reports comprehensively on a fast and simple bottom-up process to prepare supramolecular nanofibers in situ inside viscose/polyester microfiber nonwovens. Here, selected small molecules of the materials class of 1,3,5-benzenetrisamides are employed. The microfiber-nanofiber composites exhibit a homogeneous nanofiber distribution and morphology throughout the entire nonwoven scaffold. Small changes in molecular structure and processing solvent have a strong influence on the final nanofiber diameter and diameter distribution and, consequently, on the filtration performance. Choosing proper processing conditions, microfiber-nanofiber composites with surprisingly high filtration efficiencies of particulate matter are obtained. In addition, the microfiber-nanofiber composite integrity at elevated temperatures was determined and revealed that the morphology of supramolecular nanofibers is maintained compared to that of the utilized polymer nonwoven.

We report the fabrication and properties of 850 nm wavelength AlGaAs/GaAs-based transceiver chips, in which vertical-cavity surface-emitting lasers (VCSELs) and photodiodes are monolithically integrated. Various types of devices allow half-and full-duplex bidirectional optical interconnection at multiple Gbit/s data rates over a single butt-coupled glass or polymer-clad silica optical fiber with core diameters of 100 or 200 µm. Whereas metal-semiconductor-metal (MSM) photodiodes are employed for these large-area fibers, we also investigate the integration of PIN-type photodiodes which appear more promising in combination with standard 62.5 or 50 µm core diameter graded-index multimode fibers. This interconnect solution based on two identical chips is attractive owing to lower volume, weight, and cost. Applications will be found in home, in-building, industrial, or automotive networks and potentially within computer clusters or central offices.

Vertical-cavity surface-emitting lasers (VCSELs) with single-mode, single-polarization emission at a wavelength of 894.6 nm have become attractive light sources for miniaturized Cs-based atomic clocks. So far, VCSELs used for these applications are single-mode because of small active diameters which has the drawbacks of increased ohmic resistance and reduced lifetime. By employing surface grating reliefs, enhanced fundamental-mode emission as well as polarization-stable laser oscillation are achieved. VCSELs with 5 μm active diameter show side-mode suppression ratios of 20 dB even at currents close to thermal roll-over with orthogonal polarization suppression ratios better than 20 dB at elevated ambient temperatures up to 100 °C.

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