[1] Nucleation of ice crystals in the atmosphere often occurs through heterogeneous freezing processes in which an atmospheric aerosol acts as the ice nuclei (IN). Depending on the ambient conditions and composition of the available IN, heterogeneous nucleation may occur through one of several freezing mechanisms, including contact and immersion. In this study, an optical microscope apparatus equipped with a cooling stage and a digital camera was used to observe the freezing events of individual droplet-IN samples. For each experiment, a particular IN was either placed in contact with the surface or immersed in the bulk of an ultra pure water droplet. Using volcanic ash as the IN, we observed that inside-out contact freezing occurred at warmer temperatures than immersion freezing. We also conducted contact freezing experiments using three representative aerosol types as the potential IN. The most effective contact freezing IN was Pahokee Peat soil with an average freezing temperature of À10.5°C, followed by volcanic ash (À11.2°C), and finally soot (À25.6°C). In addition, we have used classical nucleation theory to derive the heterogeneous nucleation rates for the IN compositions explored.

[1] Collocated measurements of the mass concentrations of aerosol black carbon (BC) and composite aerosols near the surface were carried out along with spectral aerosol optical depths (AODs) from a high-altitude station, Manora Peak in central Himalayas, during a comprehensive aerosol field campaign in December 2004. Despite being a pristine location in the Shivalik Ranges of central Himalayas and having a monthly mean AOD (at 500 nm) of 0.059 ± 0.033 (typical to this site), total suspended particulate (TSP) concentration was in the range 15-40 mg m À3 (mean value 27.1 ± 8.3 mg m À3 ). Interestingly, aerosol BC had a mean concentration of 1.36 ± 0.99 mg m À3 and contributed $5.0 ± 1.3% to the composite aerosol mass. This large abundance of BC is found to have linkages to the human activities in the adjoining valley and to the boundary layer dynamics. Consequently, the inferred single scattering albedo lies in the range of 0.87 to 0.94 (mean value 0.90 ± 0.03), indicating significant aerosol absorption. The estimated aerosol radiative forcing was as low as À4.2 W m À2 at the surface, +0.7 W m À2 at the top of the atmosphere, implying an atmospheric forcing of +4.9 W m À2 . Though absolute value of the atmospheric forcing is quite small, which arises primarily from the very low AOD (or the column abundance of aerosols), the forcing efficiency (forcing per unit optical depth) was $88 W m À2 , which is attributed to the high BC mass fraction.

[1] During an intense field campaign for generating a spatial composite of aerosol characteristics over peninsular India, collocated measurements of the mass concentration and size distribution of near-surface aerosols were made onboard instrumented vehicles along the road network during the dry, winter season (February-March) of 2004. The study regions covered coastal, industrial, urban, village, remote, semiarid, and vegetated forestlands. The results showed (1) comparatively high aerosol (mass) concentrations (exceeding 50 mg m À3 ), in general, along the coastal regions (east and west) and adjacent to urban locations, and (2) reduced mass concentration (<30 mg m À3) over the semiarid interior continental regions. Fine, accumulation-mode particles (<1 mm) contribute more than 50% to the total aerosol mass concentration in the coastal regions, which is more conspicuous along the east coast than the west coast, while the interior regions showed abundance (>50% of the total) of coarse-mode aerosols (>1 mm). The spatial composite of accumulation-mode share to the total aerosol mass concentration agreed very well with the monthly mean spatial composite of aerosol fine-mode fraction for February 2004, deduced from Moderate-Resolution Imaging Spectroradiometer data for the study region, while a point by point comparison yielded a linear association with a slope of 1.09 and correlation coefficient of 0.79 for 76 independent data pairs. Pockets of enhanced aerosol concentration were observed around the industrialized and urban centers along the coast as well as inland. Aerosol size distributions were parameterized using a power law. Spatial variation of the retrieved aerosol size index shows relatively high values (>4) along the coast compared to interior continental regions except at a few locations. Urban locations showed steeper size spectra than the remote locations.Citation: Moorthy, K. K., et al. (2005), Wintertime spatial characteristics of boundary layer aerosols over peninsular India,

which is attributed to air trajectory effects. AngstrOm parameters, deduced from optical depth spectra, reveal a high value of o• (-0.9) for north of the ITCZ, while for the south oc is negative, indicating a change in the aerosol size distribution. Accumulation aerosols dominate in the north, while concentration of coarse aerosols remain nearly about the same, except very close to the coast. A north-south gradient in aerosol optical depth, with scaling distance of -1000 to 2000 km at shorter wavelengths and much higher at longer wavelengths, is observed. The gradient becomes shallower at high wind speeds. The large-scale dynamics associated with the movement of the ITCZ and its interannual variation appears to significantly influence the aerosol characteristics. As the southwest monsoon sets in over India, considerable wet removal and change in air mass characteristics cause a significant depletion in optical depths, which then became comparable to those prevailing in the southern hemisphere.

We present results of direct aerosol radiative forcing over a French Mediterranean coastal zone based on one year of continuous observations of aerosol optical properties during 2005-2006. Monthly-mean aerosol optical depth at 440 nm ranged between 0.1 and 0.34, with high Angstrom coefficient (α N 1.2). The single scattering albedo (at 525 nm) estimated at the surface ranged between 0.7 and 0.8, indicating significant absorption. The presence of aerosols over the Mediterranean zone during summer decreases the shortwave radiation reaching the surface by as much as 26 ± 3.9 W m − 2 , and increases the top of the atmosphere reflected radiation by as much as 5.2 ± 1.0 W m − 2 . The shortwave atmospheric absorption translates to an atmospheric heating of 2.5 to 4.6 K day − 1 . Concerted efforts are needed for investigating the possible impact of the increase in heating rate on the maintenance of heat-waves frequently occurring over this coastal region during summer time.

[1] Aerosols from the Sarychev Peak volcano entered the Arctic region less than a week after the strongest SO 2 eruption on June 15 and 16, 2009 and had, by the first week in July, spread out over the entire Arctic region. These predominantly stratospheric aerosols were determined to be sub-micron in size and inferred to be composed of sulphates produced from the condensation of SO 2 gases emitted during the eruption. Average (500 nm) Sarychev-induced stratospheric optical depths (SOD) over the Polar Environmental Atmospheric Research Laboratory (PEARL) at Eureka (Nunavut, Canada) were found to be between 0.03 and 0.05 during the months of July and August, 2009. This estimate, derived from sunphotometry and integrated lidar backscatter profiles was consistent with averages derived from lidar estimates over Ny-Ålesund (Spitsbergen). The Sarychev SOD e-folding time at Eureka, deduced from lidar profiles, was found to be approximately 4 months relative to a regression start date of July 27. These profiles initially revealed the presence of multiple Sarychev plumes between the tropopause and about 17 km altitude. After about two months, the complex vertical plume structures had collapsed into fewer, more homogeneous plumes located near the tropopause. It was found that the noisy character of daytime backscatter returns induced an artifactual minimum in the temporal, pan-Arctic, CALIOP SOD response to Sarychev sulphates. A depolarization ratio discrimination criterion was used to separate the CALIOP stratospheric layer class into a low depolarization subclass which was more representative of Sarychev sulphates. Post-SAT (post Sarychev Arrival Time) retrievals of the fine mode effective radius (r eff,f ) and the logarithmic standard deviation for two Eureka sites and Thule (Greenland) were all close to 0.25 mm and 1.6 respectively. The stratospheric analogue to the columnar r eff,f average was estimated to be r eff,f (+) = 0.29 mm for Eureka data. Stratospheric, Raman lidar retrievals at Ny-Ålesund, yielded a post-SAT average of r eff,f (+) = 0.27 mm. These results are $50% larger than the background stratospheric-aerosol value. They are also about a factor of two larger than modeling values used in recent publications or about a factor of five larger in terms of (per particle) backscatter cross section.

G lobal climate change is visibly and tangibly manifested through the Arctic cryospheric system: sea ice loss, earlier spring snowmelts, thawing permafrost, retreating glaciers, and coastal erosion. While not as visibly manifest, the role of the atmosphere is also a critical component in determining the trajectory of the Arctic system. The atmosphere not only drives change, but is reciprocally being modified through a complex web of feedbacks, and is the fast-track mechanism for the transport of energy and moisture through the global system that links climate and weather. For decades, it has been recognized that fundamental components of the atmospheric system such as clouds, atmospheric trace gases, aerosols, and atmosphere-surface exchange processes compose some of the major uncertainties that limit the diagnostic or predictive skill of coupled atmosphere-ice-ocean-terrestrial models (IPCC 2013, chapter 9). Arctic nations have responded in recent decades by establishing  A micrometeorological tower in Tiksi, Russia is used to determine the atmospheric-surface energy balance. (Photo credit: Vasily Kustov)

[1] Aerosol optical depth (AOD) measurements were acquired at six Arctic sunphotometer sites during the ARCTAS-A (April, 2008) campaign. Numerous smoke events were identified and related to extensive forest and agricultural fires in eastern Russia and northern Kazakhstan/ southwestern Russia respectively. An analysis of the fine (sub-micron) optical depths from the six stations indicated the presence of underlying low frequency trends which were coherent with general meteorological considerations, source information, model estimates and remote sensing information. Low frequency (diurnal) coarse-mode optical depth events were observed at a number of the stations; these singular events are likely due to ice particles whose nucleation may have been associated with the presence of smoke, or possibly dust.