The conditions and mechanism of formation of crosslinked polymers from furfuryl oligomers have been studied. A new mechanism of formation of crosslinked furfuryl polymers in a neutral medium is proposed. This mechanism has been confirmed experimentally by investigating reactions of formation of crosslinked polymers based on dimethylol furan oligomer.
A study was made of the conditions of heteropolycondensation of furfuryl alcohol with formaldehyde at different molar ratios. A new mechanism of formation and a new structure of furfurylformaldehyde oligomers by means of separating the initial polycondensation products are proposed. Earlier we reported on certain features of the kinetics [1] and mechanism [2] of formation of furfuryl oligomers.
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