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Colloidal suspensions of bimetallic Au/Pd nanoparticles were prepared by simultaneous reduction of the metal ions from their corresponding chloride salts with polymer (PVP) stabilizer. Thermal properties of water containing bimetallic nanoparticles with different nominal compositions (Au/Pd = 12/1, 5/1, 1/1, 1/5) were measured using the mode mismatched dual-beam thermal lens technique to determine the effect of particle composition on the thermal diffusivity of the nanofluids. The characteristic time constant of the transient thermal lens was estimated by fitting the experimental data to the theoretical expression for transient thermal lens. The thermal diffusivity of the nanofluids (water, containing Au/Pd bimetallic nanoparticles) is seen to be strongly dependent on the composition of the particles. The maximum diffusivity was achieved for the nanoparticles with highest Au/Pd molar ratio. A possible mechanism for such high thermal diffusivity of the nanofluids with bimetallic particles is given. UV-Vis spectroscopy, TEM and high-resolution electron microscopy (HREM) techniques were used to characterize the Au/Pd bimetallic nanoparticles.

A b s t r a c t. It is important to know the temperature changes in seeds that have been irradiated with laser light because this could have substantial practical and theoretical importance. Thus, the thermal effects of low intensity laser irradiation on seeds was studied, showing variation of temperature produced by laser light applied during 60 s on two maize seed genotypes, 'Toluqueño' and 'Cacahuazintle': crystalline and floury, respectively, under two different conditions: natural colour and dyed black, evaluating the temperature changes by a thermal camera. The optical absorption spectra and the non-radiative relaxation time of the seeds were obtained using photoacoustic spectroscopy. The results indicate that it is possible to produce temperature changes, detected by an infrared camera, in crystalline and floury seeds when they are irradiated with a laser beam at a 650 nm wavelength and 27.4 mW power. The highest variation of temperature in the seeds was obtained for the black-dyed condition, these variations being 5.56 and 9.28°C for crystalline and floury seeds, respectively. Among the seeds, in the dyed condition, the floury seed had the lower non-radiative relaxation time, the higher optical absorption coefficient and a lower optical penetration length at the laser wavelength (650 nm).

Thermal diffusivity measurements are carried out in nanofluids, solutions containing gold nanoparticles (∼ 10-40 nm size), using the mode-mismatched dual-beam thermal lens technique. An Ar+ laser is used as the heating source, and an intensity stabilized He-Ne laser serves as the probe beam. This technique provides a reliable photothermal alternative for measuring thermal diffusivities of nanofluids and semitransparent samples. The characteristic time constant of the transient thermal lens was obtained by fitting the experimental data to the theoretical expression for the transient thermal lens. From this characteristic time, the fluid thermal diffusivity, which increases when the particle sizes increase was obtained. The size of the nanoparticles was obtained from transmission electron microscopy (TEM) analysis.

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Photoacoustic Spectroscopy (PAS) stand outs among Photothermal techniques due to its versatility for the characterization of different types of materials, including biological samples. In this study, were compared and analyzed by PAS, the differences between the optical absorption spectra of blood of male Fisher rats, in three cases, control (healthy rats), liver damage and liver damage treated with Curcuma longa. The experimental results show differences in the optical absorption spectra of each analysed case, therefore PAS would be proposed as a non conventional complementary technique, to study the effect of Curcuma longa in induced liver damage for an animal model.