1986
DOI: 10.1002/jlac.198619861118
|View full text |Cite
|
Sign up to set email alerts
|

Zur Umlagerung von Azidomalonestern

Abstract: Dimethyl azido[6-(methoxycarbonyl)-2-oxo-2H-pyran-4-ylmethyl]malonate (4)is photolyzed under loss of nitrogen and rearrangement of one methoxycarbonyl group to form the mixture of Z und E isomers of the a,a-unsaturated amino acid esters 8 and 9. On photolysis of isopropyl-and isobutylazidomalonates 10 migration of the alkyl group is observed exclusively. The (alky1imino)malonates 14 so formed have been hydrogenated and hydrolyzed to give the N-alkylglycine derivatives 16.In der voranstehenden Arbeit 'I werden … Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

0
0
0

Year Published

1987
1987
1997
1997

Publication Types

Select...
5

Relationship

0
5

Authors

Journals

citations
Cited by 6 publications
references
References 9 publications
0
0
0
Order By: Relevance