Zinn‐organische Photoperoxyde Neue Typen metallorganischer Peroxyde

Schenck, Günther O.; Koerner, E.; Gustorf,; Köller, H.

doi:10.1002/ange.19610732107

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Syntheses Using Organotin Halides1

Allenylsllanes1

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1962

1987

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Cited by 22 publications

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“…6). Reactions with sodium chlorophenoxides [55] have been studied, as well as the preparation of organometallic peroxy compounds [56] and endoperoxides [57]. The trialkyltin halides are easily converted into the alkoxy derivatives.…”

Section: Syntheses Using Organotin Halidesmentioning

confidence: 99%

Recent Developments in Organotin Chemistry

Neumann

Burkhardt

Heymann

et al. 1963

Angew. Chem. Int. Ed. Engl.

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New synthetic methods developed in the field of organotin compounds since 1959 are reviewed. The use of alkyl aluminum compounds brings an advance in the preparation of tetraalkyltin derivatives, alkyltin halides, and alkyltin hydrides. Organotin hydrides ofer new possibilities for the production of monomeric and polymeric organotin compounds. Diethyltin and diphenyltin, which are obtained by catalytic dehydrogenation of the respective dialkyltin dihydrides, are cyclic compounds. -The literature since 1959 is reviewed.

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Section: Syntheses Using Organotin Halidesmentioning

confidence: 99%

Recent Developments in Organotin Chemistry

Neumann

Burkhardt

Heymann

et al. 1963

Angew. Chem. Int. Ed. Engl.

View full text Add to dashboard Cite

show abstract

“…sections II.B, D, and E). D. Silacycloalkenes and Germacycloalkenes (Table I, Entries 50-69, [78][79][80][81][82][83][84][85][86][87] With group 14 noncyclic allylic derivatives, the ene reaction allows one to convert an Si(Ge)-allyl group to a Si(Ge)-vinyl group; this conversion becomes especially interesting in cyclic series. Indeed, while it was initially used only for the synthesis of metallacyclopent-2enes,10-13 the ene reaction, starting with a /3-ethylenic organometallic cycloolefin, can produce an a-ethylenic cycloolefin (eq 10).…”

Section: Allenylsllanesmentioning

confidence: 99%