Water-cooling diamond anvil cells: An approach to temperature–pressure relation in heated experiments

Abstract

Temperature induced pressure drift in the diamond anvil cell (DAC) is a major issue in high-pressure high-temperature experiments. It is commonly acknowledged that these drifts originate from multiple factors, but no systematic descriptions have been made so far. By introducing an internal water-cooling system in the DAC, we have performed a systematic investigation into temperature induced pressure drifts to reveal the mechanism behind them and to find a proper experimental procedure to achieve minimal pressure variation in DAC’s heating experiment. It is revealed in this experiment that pressure variation during heating processes originates from multiple temperature related factors of the DAC. The variation itself can be considered as a rebalancing process of the compression forces on the sample chamber initiated by the disturbance caused by temperature elevation. It is possible to suppress pressure variation by maintaining the temperature of the DAC body at room temperature to ensure the consistency of compression on the sample chamber. At the same time, the best procedure for the heating experiments is to properly pre-heat the sample chamber equipped with the internal water-cooling system before performing the in situ measurements on the temperature-related properties at the pressurized and heated conditions. Our discovery provides a reliable procedure for the sample heating process in the DAC and helps resolve the complex mystery of the influence of the combination of pressure and temperature in high-pressure high-temperature experiments.

Inert structural transition in 4H and 6H SiC at high pressure and temperature: a Raman spectroscopy study

“…The diamond anvil cell was placed in the water-cooling vacuum chamber with optic glass suitable for the spectroscopic measurements to avoid the reaction of the heater with air. The water-cooling system minimized the pressure drift during heating, as shown in the previous study [25]. A stable DC power source (ZX-S-400LA, Takasago) was used for heating with a ramp rate of about 10 K min −1 .…”