“…With the deepening global energy crisis and pollution problems caused by the dwindling global fossil fuel reserves, the development of sustainable new green energy technologies has attracted widespread attention of contemporary society. − Because of its nonpolluting nature and high-energy content per mass, hydrogen energy is considered one of the most exciting future energy sources. − Among the many hydrogen production technologies, photoelectrocatalytic (PEC) hydrogen production using semiconductors as photoelectrodes to absorb solar energy and promote water splitting offers an attractive new way to solve energy problems. − In recent years, a large number of semiconductor materials, such as TiO 2, , WO 3, , Fe 2 O 3, BiVO 4, , and so on, have been applied to hydrogen water splitting operations in the field of PEC to achieve efficient hydrogen production efficiency. Nevertheless, the future applicability of PEC in water splitting has still been hampered by issues related to the high recombination rate of photogenerated charge , and the narrow light response range of the photoelectric electrodes.…”