“…Because of various advantageous characteristics, such as outstanding mechanical properties, low density, and good thermal stability, poly( p- phenylene benzobisoxazole) (PBO) fibers have been regarded as an ideal reinforcement for aerospace, defense, sports, transportation, energy management, and other areas. , To date, the main obstacle of exploiting PBO fibers is the poor interfacial compatibility and adhesion, which originates from the inherent smooth and chemical inert on the fiber surface. , As everyone knows, interfacial adhesion plays a crucial role in the load transfer nearby the interphase, the overall performance, and the service-life of composites. − The poor interfacial adhesion easily triggers the interfacial cracks and interlaminar failure under the transverse load. , In a word, the nonideal interfacial behaviors of PBO fibers composites make up one of the bottleneck problems during the development of advanced composites …”