1981
DOI: 10.1016/s0040-4020(01)97987-6
|View full text |Cite
|
Sign up to set email alerts
|

Utilisation en synthese du cation iminium genere in situ par oxydation electrochimique d'amines tertiaires

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1

Citation Types

0
9
0

Year Published

1983
1983
2022
2022

Publication Types

Select...
5
2

Relationship

0
7

Authors

Journals

citations
Cited by 28 publications
(9 citation statements)
references
References 23 publications
0
9
0
Order By: Relevance
“…[39] Later, the groups of Dinnocenzo, Fari, and Gould quantified Genies assumption and calculated a twist angle of 428 between the aryl ring and the dimethyl-A C H T U N G T R E N N U N G amino group in the radical cation 1lC…”
Section: A-phosphonationmentioning
confidence: 99%
“…[39] Later, the groups of Dinnocenzo, Fari, and Gould quantified Genies assumption and calculated a twist angle of 428 between the aryl ring and the dimethyl-A C H T U N G T R E N N U N G amino group in the radical cation 1lC…”
Section: A-phosphonationmentioning
confidence: 99%
“…This 6-effect of 4.9 ppm is comparable with the 6-effect of 5 ppm observed for 2-methyl cyclohexane (12). The carbonyl carbon appears at 214.68 ppm and 212.97 ppm for the axial and the 4~ complete study on the electrochemical oxidation of N,N-dimethylrneiidine in the presence of nucleophiles has been published (7,8).…”
Section: Resultsmentioning
confidence: 99%
“…Recently, it 3 was shown that the iminium cation, obtained from the electrochemical oxidation of N,N-dimethylanilines, gave good yields of addition products with nucleophiles such as diethyl phos-R ' 1 I phate and dialkylmalonates (7,8). It seemed to be interesting \N-CH~-C-C-R~ for us to study the preparation of Mannich bases 4 by the R2"…”
Section: // ' C=c \Rsmentioning
confidence: 99%
See 1 more Smart Citation
“…10 A different method to afford a-aminophosphonates especially from the tertiary amines is the cross-dehydrogenative-coupling (CDC) reaction between a sp 3 C-H bond adjacent to a nitrogen atom and a P-H bond. In 1981, Genies and co-workers 11 reported a CDC reaction of dialkyl phosphonates with tertiary amines through electrical oxidation albeit with moderate yields. In 2001, Tilley and co-workers 12 reported an intramolecular C-H/P-H dehydrogenative coupling catalyzed by Rh complex.…”
mentioning
confidence: 99%