Water desalination
performance of capacitive deionization (CDI)
largely depends on electrode materials properties. Rational design
and regulation of the structure and composition of electrode materials
to acquire high CDI performance is of great significance. Herein,
nitrogen-doped hollow mesoporous carbon spheres (N-HMCSs) were investigated
as electrode material for CDI application. To understand the effect
of structure and composition on CDI performance, another two CDI electrode
materials, i.e., hollow mesoporous carbon spheres (HMCSs) and solid
mesoporous carbon spheres (SMCSs) were prepared for comparison. The
obtained N-HMCSs possessed unique hollow cavity and excellent nitrogen
doping property, resulting in fast ion diffusion, good charge transfers
ability and fine wettability. Compared with HMCSs and SMCSs electrodes,
N-HMCSs electrode exhibited an improved electrosorption capacity and
rate, demonstrating the dependence of CDI performance on the synergistic
effect of hollow structure and nitrogen doping property. N-HMCSs electrode
also present excellent cycle stability over 20 adsorption–desorption
cycles. These results indicate the promising prospect of N-HMCSs for
CDI application.