Ultrasensitive electrochemical detection of furazolidone in biological samples using 1D-2D BiVO4@MoS2 hierarchical nano-heterojunction composites armed electrodes

Maheshwaran, Selvarasu; Balaji, Ramachandran; Chen, Shen‐Ming; Chang, Yo-Shiuan; Tamilalagan, Elayappan; Chandrasekar, Narendhar; Ethiraj, Selvarajan; Samuel, Melvin S.; Mohanraj, K.

doi:10.1016/j.envres.2021.112515

Cited by 31 publications

(14 citation statements)

References 50 publications

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“…The antisymmetric and symmetric V−O stretching vibrations lead to a sharp peak positioned at ∼843 cm −1 along with an ∼752 and ∼723 cm −1 shoulder band. 30 The Raman spectra obtained for the MoS 2 @ BiVO 4 composite establish all the main bands characteristic of BiVO 4 and MoS 2 . Additionally, as a consequence of the composite formation, a red shift is observed in the vibration modes of MoS 2 @BiVO 4 as compared to peak centers of pristine BiVO 4 and MoS 2 .…”

Section: ■ Results and Discussionmentioning

confidence: 69%

“…00-014-0133 (unit cell parameters: a = 7.300 A°, c = 6.457 A°; space group: I4 1 /amd). 30,61 The patterns fit well with tetragonal BiVO 4 (red) and displayed well-distinguished peaks at 18.9°, 28.9°, 30.6°, 34.6°, 35.2°, 39.9°, 42.4°, 46.8°, 47.3°, 50.2°, 53.4°, and 58.4°, attributable to the (110), (011), ( 121), (040), ( 200), (002), ( 211), (015), (240), (042), (161), and (321) planes characteristic of tetragonal BiVO 4 structures. The stabilization and activity enhancement of the tetragonal phase can be correlated with the selection of lower reaction temperature and composite formation as previously reported by various researchers.…”

Section: ■ Results and Discussionmentioning

confidence: 99%

“…A hydrothermal route was adopted for the synthesis of 2D MoS 2 nanostructures. 30 Stoichiometric ratio of Na 2 MoO 4 , thiourea, and oxalic acid were dissolved in 80 mL of DI water and stirred for 20 min. The final solution was transferred to a Teflon cup and annealed at 180 °C for 24 h. The sample was allowed to cool down to room temperature, and the blackcolored product was centrifuged using DI water and ethanol.…”

Section: ■ Materials and Methodsmentioning

confidence: 99%

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In Situ Synthesis of a Bismuth Vanadate/Molybdenum Disulfide Composite: An Electrochemical Tool for 3-Nitro-l-Tyrosine Analysis

et al. 2022

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The quantification of 3-nitro-l-tyrosine (NO2-Tyr), an in vivo biomarker of nitrosative stress, is indispensable for the clinical intervention of various inflammatory disorders caused by nitrosative stress. By integrating the unique features of BiVO4 and MoS2 with matching bandgap energies, electrode materials with amplified response signals can be developed. In this regard, we introduce a hydrothermally synthesized bismuth vanadate sheathed molybdenum disulfide (MoS2@BiVO4) heterojunction as a highly sensitive electrode material for the determination of NO2-Tyr. Excellent electrochemical behavior perceived for the MoS2@BiVO4 augments the performance of the sensor and allows the measurement of NO2-Tyr in biological media without any time-consuming pretreatments. The synergistic interactions between BiVO4 and MoS2 heterojunctions contribute to low resistance charge transfer (R ct = 159.13 Ω·cm2), a reduction potential E pc = −0.58 V (vs Ag/AgCl), and a good response range (0.001–526.3 μM) with a lower limit of detection (0.94 nM) toward the detection of NO2-Tyr. An improved active surface area, reduced charge recombination, and high analyte adsorption contribute to the high loading of the biomarker for improved selectivity (in the presence of 10 interfering compounds), operational stability (1000 s), and reproducibility (six various modified electrodes). The proposed sensor was successfully utilized for the real-time determination of NO2-Tyr in water, urine, and saliva samples with good recovery values (±98.94–99.98%), ascertaining the reliability of the method. It is noteworthy that the electrochemical activity remains unaffected by other redox interferons, thus leading to targeted sensing applications.

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Section: ■ Results and Discussionmentioning

confidence: 69%

Section: ■ Results and Discussionmentioning

confidence: 99%

Section: ■ Materials and Methodsmentioning

confidence: 99%

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In Situ Synthesis of a Bismuth Vanadate/Molybdenum Disulfide Composite: An Electrochemical Tool for 3-Nitro-l-Tyrosine Analysis

et al. 2022

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“…In addition, the sensor achieved ideal recoveries for simultaneous determination of FZD (95.85–103.9%) and CAP (95.72–104.4%) in milk and honey by standard addition method. Maheshwaran al ( Maheshwaran et al, 2022 ). Using hydrothermally synthesized BiVO 4 @MoS 2 hierarchical nanoheterojunction composites to develop an electrochemical sensor for FZE detection by modifying glassy carbon electrode (GCE) as a novel electrocatalyst.…”

Section: Research Progress Of Immunosensorsmentioning

confidence: 99%

Immunosensor of Nitrofuran Antibiotics and Their Metabolites in Animal-Derived Foods: A Review

Jia

Zhang

et al. 2022

Front. Chem.

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Nitrofuran antibiotics have been widely used in the prevention and treatment of animal diseases due to the bactericidal effect. However, the residual and accumulation of their metabolites in vivo can pose serious health hazards to both humans and animals. Although their usage in feeding and process of food-derived animals have been banned in many countries, their metabolic residues are still frequently detected in materials and products of animal-derived food. Many sensitive and effective detection methods have been developed to deal with the problem. In this work, we summarized various immunological methods for the detection of four nitrofuran metabolites based on different types of detection principles and signal molecules. Furthermore, the development trend of detection technology in animal-derived food is prospected.

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“…Therefore, electrochemical sensors are more advantageous due to their low cost, rapid response, user-friendly and on-site detection. Recently, Bao-Shan He et al modified graphene and Au nanoparticles [1], Selvarasu Maheshwaran et al developed 1-Dimensional (1D)-2-Dimensional (2D) BiVO 4 @MoS 2 [7], and Chellapandi et al developed a 3D hierarchical CuS-rGO/g-C 3 N 4 nanostructure [8] for the electrochemical detection of FZE.…”

Section: Introductionmentioning

confidence: 99%

Fabrication of a New Electrochemical Sensor Based on Bimetal Oxide for the Detection of Furazolidone in Biological Samples

et al. 2022

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This study utilized a simple hydrothermal method to synthesize nickel molybdenum oxide (NMO) for the detection of furazolidone (FZE). Our synthesized NMO was characterized by X-Ray diffraction (XRD), X-Ray photoelectron spectroscopy (XPS), Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR), field emission scanning electron spectroscopy (FE-SEM), and energy dispersive X-Ray spectroscopy (EDX). The cyclic voltammetry (CV) and differential pulse voltammetry (DPV) were used to detect the FZE. Under optimized conditions, the obtained results showed that the NMO had an excellent electrocatalytic property towards FZE. As a result, NMO/GCE showed a good linear range of 0.001–1765 µM, an excellent detection limit (LOD) of 0.02 µM, and sensitivity of 0.2042 µA µM−1 cm−2.

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Ultrasensitive electrochemical detection of furazolidone in biological samples using 1D-2D BiVO4@MoS2 hierarchical nano-heterojunction composites armed electrodes

Cited by 31 publications

References 50 publications

In Situ Synthesis of a Bismuth Vanadate/Molybdenum Disulfide Composite: An Electrochemical Tool for 3-Nitro-l-Tyrosine Analysis

In Situ Synthesis of a Bismuth Vanadate/Molybdenum Disulfide Composite: An Electrochemical Tool for 3-Nitro-l-Tyrosine Analysis

Immunosensor of Nitrofuran Antibiotics and Their Metabolites in Animal-Derived Foods: A Review

Fabrication of a New Electrochemical Sensor Based on Bimetal Oxide for the Detection of Furazolidone in Biological Samples

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