A zinc-blende (ZB) AlN and wurtzite (WZ) GaN mixed-phase (AGMP) nanostructured film was prepared by pulsed laser deposition on n-type Si (100) substrates. Compared with single-phase AlN or GaN film for field emission properties, the turn-on field of AGMP film is lowered from 17.8 to 1.2 V/μm at 1 μA/cm2, and the FE current density of AGMP is raised up about four orders of magnitude. The striking FE enhancement effect of the mixed-phase structure may be partially originated from an efficient electron step-transport in mixed phase, which provides a most favorable emission energy level and greatly advances the supply of effective FE electrons. In addition, the AGMP nanofilm may help with electron transport, which is very different from the mixtures of ZB and WZ nanowires blocking electron transport in the recent report [Nano Lett.
2011, 11, 2424].