Abstract:Glyoxel-di(tert-butylnitron)(1) reagiert mit Benzylisothiocyanat (2) auBer zu 3 und 5 zu dem benzylthiocarbamoylierten Derivat 10 eines 2-( tert-Buty1imino)-acetamidins, das authentisch aus dem mono-Desoxygenierungsprodukt 6 und der Amidin-Zwischenstufe 9B synthetisiert werden kann.
Reaction of Glyoxal Di(tert-butylnitrone) with Benzyl IsothiocyanateThis reaction leads to the formation of three products: the expected compound 3, a 3-thioxo-l,2,4thiadiazolidin-5-one 5, and the thiocarbamoylated derivative 10 of… Show more
Das Glyoxalnitron (I) reagiert mit Benzylisothiocyanat (II) zum Thiadiazolidinonthion (III), zum Bi‐oxadiazolidinthion (IV) und zu einem der isomeren Amidinothiocarbamide (V) oder (VI).
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