2014
DOI: 10.1039/c4ta02666g
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Triple-shelled Mn2O3hollow nanocubes: force-induced synthesis and excellent performance as the anode in lithium-ion batteries

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Cited by 98 publications
(54 citation statements)
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“…Over the past years, fabrication of electrode materials with hollow micro-/nanostructures has been ubiquitous since their widespread characteristics including high surface areas and void ratios can effectively improve the diffusion kinetics by reducing the penetration pathways of electrolyte and lithium ions into the electrode materials, allowing these materials to exhibit remarkable cycling and rate capability [15,16]. Generally, the universal strategies for the controllable generation of hollow structures have been based on the templating methods, by encapsulating various templates (e.g.…”
Section: Introductionmentioning
confidence: 99%
“…Over the past years, fabrication of electrode materials with hollow micro-/nanostructures has been ubiquitous since their widespread characteristics including high surface areas and void ratios can effectively improve the diffusion kinetics by reducing the penetration pathways of electrolyte and lithium ions into the electrode materials, allowing these materials to exhibit remarkable cycling and rate capability [15,16]. Generally, the universal strategies for the controllable generation of hollow structures have been based on the templating methods, by encapsulating various templates (e.g.…”
Section: Introductionmentioning
confidence: 99%
“…[12,13] While attaining significant interest in many fields of research, dimanganese trioxide has primarily been investigated as a water splitting catalyst, electrodes for lithium ion batteries, and supercapacitors. [14][15][16][17] Based on literature, Mn 2 O 3 has relatively high conductivity, thermodynamic stability and a reported band gap of 1.2eV, which makes it a suitable material for optoelectronics and photovoltaic applications. [18] So far, several deposition techniques of Mn 2 O 3 were reported in literature such as hydrothermal, facile solvothermal, calcination and reduction of MnO 2 .…”
Section: Introductionmentioning
confidence: 99%
“…Lithium ion batteries have been widely used in portable electronics (including mobile phones,l aptops, and digitala udio players), and are expected to be ap romisingp ower source in electric vehicles due to their superiore nergy density compared to other secondary batteries. [1] To meet the increasing energy density demands in large-scale energy-storage devices, research has been focused on new electrode materials with large capacityd ensity and long cycling stabilityf or the lithium ion battery.V arious transition metal oxides,s uch as Fe 3 O 4 , [2] Fe 2 O 3 , [3] Co 3 O 4 , [4] SnO 2 , [5] MoO 2 , [6] TiO 2 , [7] and Mn 2 O 3 [8] have been proposed as anode materials because of their high capacity or good cycling performance. Amongt he transition metal oxides, tungsten trioxide( WO 3 )w ith at heoretical capacity of 693 mAh g À1 offers unique advantages: av ery large volumetric capacityd ensity,5 274 mAh cm À3 ,d ue to its vast theoretical mass density (7.61 gcm À3 ), and lower cost.…”
Section: Introductionmentioning
confidence: 99%