Si heterojunction solar cells based on organic and transition metal oxide selective carrier contact (SCC) layer are developed to bypass the high temperature diffusion process required for the fabrication of p-n junction in conventional Si solar cell. In this work, we design, simulate, fabricate and characterize Si heterojunction solar cells based on organic material, poly(3,4-ethylenedioxythiophene) : polystyrenesulphonate (PEDOT:PSS), and transition metal oxide, molybdenum oxide (MoOx). To have an in-depth understanding of the n-Si/PEDOT:PSS hybrid solar cell, we characterize the heterojunction by reverse recovery transient (RRT) and DC I-V techniques to ascertain its nature. Solar cells are fabricated by spin coating PEDOT:PSS solution on top of n-Si with various doping concentrations (ND) from 10 14-10 17 cm-3. The results of RRT measurement contradicts the Schottky junction model that is commonly assumed for such heterojunction. Instead the n-Si/PEDOT:PSS junction act consistently with the n-p + junction model. The forward bias current injection level is found to influence τp, attributed to the trap saturation effect at n-Si and PEDOT:PSS interface. The interpretation of n-p + junction model is also consistent with DC-IV measurement. Photovoltaic measurement of the n-Si/PEDOT:PSS hybrid solar cell has been conducted to understand the effect of ND on solar cell performance.