A three-dimensional study is made to improve the theoretical approach of spectral response of bifacial polycrystalline silicon solar cells. This study has allowed taking into account new parameters like grain size and grain boundaries recombination velocity, which reduce the cell efficiency. Losses in emitter region and external magnetic field are also being taken into account in order to perfect the description of measured spectral response. Then the new analytical expressions of carrier, photocurrent and short circuit densities are produced for front side and rear side illuminations. Homemade software based on the new analytical expressions of internal quantum efficiency is used to fit the experimental data.
PACS:73.50.Pz KEYWORDS: 1-Spectral response; 2-Polycrystalline; 3-Solar cell; 4-Magnetic field.
INTRODUCTIONThe spectral response (SR) data are useful to determine the quality of solar cells. From the SR, one can determine fundamental parameters of solar cells like: effective diffusion length (L eff ), effective lifetime (τ eff ), back surface recombination velocity (S B ), which are used in the characterization above. There exists a lot of techniques of characterization using SR data, but each of them uses its own theoretical approach of SR. We can cite the linear fit method (Warta, 1992.), (Werner, et al., 1993), (Basu and Singh, 1994, pp.317-329), (Spiegel, et al., 2000), (Tool et al., 2002); its application leads to L eff directly and is suitable for solar cells where L eff is much smaller than the base region thickness.The theoretical approach of SR is better in producing accurate values of fundamental parameters. Thereby, the other parameters must be taken into account to describe SR especially for the polycrystalline silicon solar cells (Lu, et al., 2003) (Fedorov, et al., 2002, pp.49-55), which are mainly used in terrestrial applications. The grain size and the grain boundaries recombination velocity (S g ) (Lu, et al., 2003) (Ba, et al., 2003, pp.143-154) in polycrystalline silicon solar cells are important parameters which affect its efficiency.During the SR measurement (Spiegel, et al., 2000), the influences of external conditions like the temperature and the magnetic field intensity are not outdone.In this paper we make a new theoretical approach of the spectral response through a three dimensional study. In order to improve the SR, we are taking into account the contribution of emitter region, grain size, grain boundaries (GBs) recombination velocity, and an external magnetic field. We also apply a new technique to determine the recombination parameters based on new expressions of spectral response by fitting experimental data. This work is split into three parts: in the first part we have the theory that leads to the internal quantum efficiency, then in the second part we investigate the influence of magnetic field and GBs recombination and in the last part we present the new method and the results of its application.
MODELLING
Model and assumptionsIn this study, we use a sampl...