KEY WORDS:weak links, bicrystals, EELS, YBa2CU307_,S, grain boundary structure A BSTRACT Grain-boundary weak links limit the critical current density of poly crystalline high-Tc superconductors. Themes that have evolved from research on these grain boundaries include (a) an apparent general and dramatic distinction between the behavior of low-angle and high-angle grain boundaries, (b) electrical heterogeneity along as well as among boundaries, (c) indications that the macroscopic current path may or may not cross certain high-angle grain boundaries, (d) a key role for TEM EELS in studies of the electronic structure near grain boundaries, and (e) evidence that current models for grain boundary structure pertain to the high-Tc superconductors and may eventually help us to understand their electromagnetic character. Results regarding each of these topics are reviewed in this paper. 0084-6600/95/0801-0193$05.00 193 Annu. Rev. Mater. Sci. 1995.25:193-222. Downloaded from www.annualreviews.org by University of Massachusetts -Amherst on 09/27/12. For personal use only. Quick links to online content Further ANNUAL REVIEWS Annu. Rev. Mater. Sci. 1995.25:193-222. Downloaded from www.annualreviews.org by University of Massachusetts -Amherst on 09/27/12. For personal use only. (HIGH-Tel SUPERCONDUCTOR GRAIN BOUNDARIES [> EPITAXY OF DISSIMILAR MATERIALS, C. J. Palmstrnm 389 V11 Annu. Rev. Mater. Sci. 1995.25:193-222. Downloaded from www.annualreviews.org by University of Massachusetts -Amherst on 09/27/12. For personal use only. Quick links to online content Further ANNUAL REVIEWS