“…For example for our films grown on NGO phase and orientation evolution with growth temperature is presented in Fig. The reason for formation of several phases/orientations were investigated for the non c-axis Bi-22 1 2 films and can be summarized as follows: substrate non-uniformity (domains with different roughness giving thermodynamically preferred growth orientations) [4], mismatch strain between film and substrate [4], low difference in the free energy between Bi-2201, Bi-2212 and Bi-2223 phases [4], orientation and type of the substrate resulting in different substrate-film bonding at interface and therefore inducing homo-(when strong ionic bonds S-F form) or hetero-epitaxial (when weak Van der Waals bonds S-F form) growth [4], the thermodynamic stability (anisotropic growth kinetics) and epitaxy at the F-S interface combined with the half-unit cell stability of the HTS (understood from the viewpoint of the electrical neutrality) that is different when the interface layer is Bi-O sheet or the perovskite layer which consist of Sr, Ca and Cu [7]. The growth temperatures indicated here are to some extent relative because from one experiment, or MOCVD equipment to another the arrangements are not perfectly identical.…”