1999
DOI: 10.1039/a904379i
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Total synthesis of (+)-rottnestol†

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Cited by 11 publications
(4 citation statements)
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“…from Rottnest Island, Western Australia, 172 has been proposed on the basis of total synthesis. 173 Six additional acetylenic enol ethers, petroraspailynes A1 202, A2 203, A3 204, B1 205, B2 206 and B3 207, and the alcohol 208, the absolute configurations of which were determined by Mosher's method, have been isolated from a Korean species of Petrosia. 174 Seven additional cytotoxic polyacetylenes, (3S,14S)-petrocortyne A 209, petrotetrayndiols A 210, B 211 and C 212, dideoxypetrosynols E 213 and F 214, and nor-3S,14S-petrocortyne A 215, were also isolated from a Petrosia sp.…”
Section: Spongesmentioning
confidence: 99%
“…from Rottnest Island, Western Australia, 172 has been proposed on the basis of total synthesis. 173 Six additional acetylenic enol ethers, petroraspailynes A1 202, A2 203, A3 204, B1 205, B2 206 and B3 207, and the alcohol 208, the absolute configurations of which were determined by Mosher's method, have been isolated from a Korean species of Petrosia. 174 Seven additional cytotoxic polyacetylenes, (3S,14S)-petrocortyne A 209, petrotetrayndiols A 210, B 211 and C 212, dideoxypetrosynols E 213 and F 214, and nor-3S,14S-petrocortyne A 215, were also isolated from a Petrosia sp.…”
Section: Spongesmentioning
confidence: 99%
“…5 Among the materials investigated were polymers such as thermoplastic polyurethanes, silicone-polycarbonate block copolymers, ethylene-vinyl acetate copolymers, flexible polyesters, and various thermoplastic elastomers and polyolefin blends. 6 We also tried to solve the problem of the toxicity of plasticized PVC by use of a polyurethane (PU) and polypropylene (PP) blend as a blood bag material. PUs are one of the few synthetic materials with good biocompatibility and other performance characteristics, which make them suitable for a wide range of medical application such as for blood bags and surgical gloves and for a wide range of high-risk applications such as catheters, synthetic veins, and, more recently, wound dressings.…”
Section: Introductionmentioning
confidence: 99%
“…The structure of 204 was elucidated on the basis of 1 H, 13 C, COSY, HSQC, HMBC and NOE NMR studies [ 81 ]. The stereochemistry at C-12 was subsequently determined by total synthesis [ 82 ].…”
Section: Discussionmentioning
confidence: 99%