TiO₂ supported cobalt oxide for olefin epoxidation reaction – characterization, catalytic activities and mechanism – using a DFT model

Abstract

Conversion of olefin to epoxide: Surface acidic sites of the catalysts allow the electron rich olefin to get adsorb on the catalyst and facilitate the bond cleavage to form epoxides.

Photocatalytic dehydrogenation of ammonia borane over Ti3C2/MOF-supported Pd-doped Co nanoparticles

“…40 The characteristic Co 2p spectrum was deconvoluted into the peaks at 779.8, 795.5, 781.1, and 796.9 eV, assigned to Co( ii ) 2p 3/2 , Co( ii ) 2p 1/2 , Co( iii ) 2p 3/2 , and Co( iii ) 2p 1/2 , respectively. 41 And two satellite peaks were located at 785.5 and 802.4 eV. It should be noted that the XPS peaks of Pd 3d usually overlap with those of Zr 3p, in agreement with the reported work.…”