1993
DOI: 10.1063/1.110586
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Time-modulated electron cyclotron resonance plasma discharge for controlling generation of reactive species

Abstract: This study examines modulated electron cyclotron resonance (ECR) plasma discharge occurring within a few tens of μs. It can control the generation of reactive species in plasmas. Reactive species are measured by an actinometric optical emission spectroscopy in the pulsed plasma. Good correlation is found between the density ratio of CF2 radicals and F atoms in the CHF3 plasma, and the combination of the pulse duration and pulse intervals. These characteristics are explained by the dependence of reactive specie… Show more

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Cited by 117 publications
(63 citation statements)
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“…The pulse discharge has been sometimes used in diagnostic measurements; 3,4 however, some interesting results for material processing have been also reported. [5][6][7][8][9][10][11][12][13][14][15][16][17] The control of electron energy was also demonstrated in a microwave discharge tube 18 and time resolved measurements of electron temperature were carried out in an electron cyclotron resonance ͑ECR͒ discharge. 19 The pulse modulated ECR discharge has been also applied for CVD 15,16 or etching.…”
Section: S Okadamentioning
confidence: 99%
“…The pulse discharge has been sometimes used in diagnostic measurements; 3,4 however, some interesting results for material processing have been also reported. [5][6][7][8][9][10][11][12][13][14][15][16][17] The control of electron energy was also demonstrated in a microwave discharge tube 18 and time resolved measurements of electron temperature were carried out in an electron cyclotron resonance ͑ECR͒ discharge. 19 The pulse modulated ECR discharge has been also applied for CVD 15,16 or etching.…”
Section: S Okadamentioning
confidence: 99%
“…In principle, non-stationary excitation conditions caused by time dependent energy supply into the plasma can be used to manipulate the density and energy distribution of electrons and to achieve modified chemical equilibria [18,19]. As a result with pulsed plasmas higher chemical conversion rates but also improved etching and deposition processes can be realized [20][21][22][23][24].…”
Section: Introductionmentioning
confidence: 99%
“…However, it is quite difficult to change the electron energy in weakly ionized plasma because the particle balance between the plasma generation and loss automatically determines the electron temperature. Therefore, the electron temperature is not simply changed by the input power at a fixed pressure [20]. We here change the particle balance by separating the discharge spatially under a constant gas pressure [21].…”
Section: Electron Temperature Control Of Plasmasmentioning
confidence: 98%