Monolithic integration of AlGaN/GaN high electron mobility transistor (HEMT) into silicon (Si) platform is very attractive as this is a cost-effective solution to extend the capabilities of silicon technology especially for high power and high frequency applications. It is not only that Si substrate is cheaper than other commonly used substrates for GaN epitaxy such as Sapphire and SiC but growing on Si substrate also allows integration with current Si technology in the industry. Unfortunately, this technology is still very limited by its associated reliability issues. This study focused on depletion-mode (D-mode) AlGaN/GaN HEMT devices on Si with negative threshold voltage (VTH) of about −3 V. AlGaN/GaN HEMT reliability can be divided into OFF-state and ON-state reliabilities. AlGaN/GaN HEMT ON-state reliability is not as well reported as OFF-state reliability. Therefore, this thesis aims to fill up the knowledge gap in AlGaN/GaN HEMT ON-state reliability. This study has three main objectives. The first objective is to comprehend the electrical and physical degradation mechanism in AlGaN/GaN HEMT devices stressed under ON-state condition. The second objective is to understand the effects of stressing and process parameters on AlGaN/GaN HEMT ON-state degradation. Finally, this study aims to develop a reliability model based on the degradation mechanism in AlGaN/GaN HEMT stressed under ON-state condition. OFF-state and ON-state degradations were compared in Chapter 4. It was observed that devices stressed under ON-state condition degraded faster than similar devices stressed under OFF-state condition with higher stressing temperature. This is because of the occurrence of electro-chemical oxidation of AlGaN away from the gate edge during ONstate stressing. Dark features containing gallium, aluminum and oxygen were found at the AlGaN/SixN1-x interface away from the gate edge on the drain side of the ON-state-stressed devices. These oxidized portions of AlGaN were etched away during metallization and passivation layer etching leaving behind pits at the drain-gate access region. The total area W/mm [48] power density while AlGaAs/GaAs HEMT can only operate up to 200°C and 1.5 W/mm. Figure 1.1 Performance comparison between GaN-, GaAs-and Si-based transistors assuming all transistors have the same packaging [9] 1.1.1 AlGaN/GaN HEMT Working Principle AlGaN/GaN HEMT epitaxy can be grown by both molecular beam epitaxy (MBE) [49-53] and metal-organic chemical vapor deposition (MOCVD) [54-58]. The performance of the MBE-grown device is comparable to the MOCVD-grown device [59]. However, in the long run, MBE is more costly than MOCVD. Therefore, MOCVD is preferred over MBE to grow AlGaN/GaN HEMT commercially. AlN and GaN have a wurtzite-type hexagonal crystal structure [60]. Two types of GaN epitaxy can be grown depending on the cut-face of the GaN i.e. Ga-polar and N-polar. Gapolar film is usually grown by MOCVD whereas N-polar film is usually grown by MBE under certain conditions [61]. The devices used in this study are Ga...