Thin Film Deposition of Organic−Inorganic Hybrid Materials Using a Single Source Thermal Ablation Technique

Mitzi, David B.; Prikas, and M. T.; Chondroudis, Konstantinos

doi:10.1021/cm9811139

Cited by 191 publications

(147 citation statements)

References 15 publications

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“…In the late 1990s, vacuum deposition and thermal ablation methods have been developed to fabricate HOIPs thin films for stoichiometry control and 2-D quantum well. [23][24][25] In this manuscript, we will review the HOIP solar cells that are made with vapor deposition or reaction process. The various methods are classified as shown in Figure 1.…”

mentioning

confidence: 99%

Research Update: Hybrid organic-inorganic perovskite (HOIP) thin films and solar cells by vapor phase reaction

Shen

Chiang

et al. 2016

APL Materials

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With the rapid progress in deposition techniques for hybrid organic-inorganic perovskite (HOIP) thin films, this new class of photovoltaic (PV) technology has achieved material quality and power conversion efficiency comparable to those established technologies. Among the various techniques for HOIP thin films preparation, vapor based deposition technique is considered as a promising alternative process to substitute solution spin-coating method for large-area or scale-up preparation. This technique provides some unique benefits for high-quality perovskite crystallization, which are discussed in this research update.

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mentioning

confidence: 99%

Research Update: Hybrid organic-inorganic perovskite (HOIP) thin films and solar cells by vapor phase reaction

Shen

Chiang

et al. 2016

APL Materials

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“…[63] . [67,68] , 在 2013 年, 基于沉积技术条件的优化, Liu 等使用双源蒸发沉积技术来制备在平面异质结太阳电池中充当吸收层的混合卤素钙钛矿 [69] , 结果显示, 溶液加工的钙钛矿膜仅部分覆盖着基片, 针孔多且覆盖率低, 蒸发沉积所得的钙钛矿薄膜形成非常统一整齐的纳米尺寸晶块, 获得无任何针孔的非常均匀的钙钛矿膜, 制备出 V oc ＝1.07 V, [70,71] . [60] .…”

Section: 两步顺序沉积法unclassified

Recent Advances in Perovskite Solar Cells: Morphology Control and Interfacial Engineering

Xue

Sun

et al. 2015

Acta Chim. Sinica

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Organic-inorganic hybrid perovskite solar cells are considered as a promising new generation photovoltaic technology that can be produced with very low cost. Recent studies revealed that organometal trihalide perovskite semiconductors exhibit several desired properties for photovoltaic applications including high absorption coefficient, low exciton binding energy, long carrier-diffusion lengths and facile tunable bandgaps, enabling their efficiencies leap from less than 5% to ca. 20% in small area devices in the past 5 years. Module efficiency up to 8.7% was also demonstrated, paving the way for potential commercialization of this new photovoltaic technology. In this review article, we discussed two important factors that had been employed to improve perovskite solar cell performance including morphology control of the perovskite films through advanced processing methods and also interface engineering in both conventional-type and inverted-type device structures. We also discussed the scientific and technological challenges remained to be solved before perovskite solar cells can be considered for real applications.

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“…Usual way of fabricating these thin films is from spin-coating of IO-hybrid solutions onto a desired substrate. Although other techniques like single-and double-source thermal vapor deposition, Langmuir Blodgett (LB) method, layer by layer deposition, spray pyrolysis, and low-temperature melting process had been employed to obtain films, it is always difficult to find empirical conditions and processes to obtain well-ordered thin films of these IO-hybrids [95][96][97][98][99][100]. Especially the applicability of thermal vapor deposition technique is limited due to stability and contamination issues and to balance organic and inorganic evaporation rates simultaneously.…”

Section: General View Of Synthesis Fabrication and Implicationsmentioning

confidence: 99%

Naturally Self-Assembled Nanosystems and Their Templated Structures for Photonic Applications

Kannan

Kotla

Ahmad

et al. 2013

Journal of Nanoparticles

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Self-assembly has the advantage of fabricating structures of complex functionalities, from molecular levels to as big as macroscopic levels. Natural self-assembly involves self-aggregation of one or more materials (organic and/or inorganic) into desired structures while templated self-assembly involves interstitial space filling of diverse nature entities into self-assembled ordered/disordered templates (both from molecular to macro levels). These artificial and engineered new-generation materials offer many advantages over their individual counterparts. This paper reviews and explores the advantages of such naturally self-assembled hybrid molecular level systems and template-assisted macro-/microstructures targeting simple and low-cost device-oriented fabrication techniques, structural flexibility, and a wide range of photonic applications.

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Thin Film Deposition of Organic−Inorganic Hybrid Materials Using a Single Source Thermal Ablation Technique

Cited by 191 publications

References 15 publications

Research Update: Hybrid organic-inorganic perovskite (HOIP) thin films and solar cells by vapor phase reaction

Research Update: Hybrid organic-inorganic perovskite (HOIP) thin films and solar cells by vapor phase reaction

Recent Advances in Perovskite Solar Cells: Morphology Control and Interfacial Engineering

Naturally Self-Assembled Nanosystems and Their Templated Structures for Photonic Applications

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