The reaction kinetics of diglycidyl ether of bisphenol A (DGEBA) cured with different concentrations of imidazole and bisphenol A (BPA) were investigated by using differential scanning calorimetry. Both dynamic and isothermal DSC were studied. Two initiation mechanisms were found to play roles in the curing reactions. One was based on adduct formation of epoxy groups with pyridine‐type nitrogen and the other was based on ionic complexes of imidazole and BPA. The subsequent propagation was composed of three main reactions, viz. the epoxide/phenol reaction, the acid/base reaction, and the epoxide/R‐O− reaction. A generalized kinetics model was developed and used to predict the conversion of epoxide groups using a wide range of imidazole and BPA concentrations, and cure temperature. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 3233–3242, 1999