2011
DOI: 10.1007/s12613-011-0487-9
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Thermal conductivity model of filled polymer composites

Abstract: Theoretical and empirical models for predicting the thermal conductivity of polymer composites were summarized since the 1920s. The effects of particle shape, filler amount, dispersion state of fillers, and interfacial thermal barrier on the thermal conductivity of filled polymer composites were investigated, and the agreement of experimental data with theoretical models in literatures was discussed. Silica with high thermal conductivity was chosen to mix with polyvinyl-acetate (EVA) copolymer to prepare SiO 2… Show more

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Cited by 58 publications
(39 citation statements)
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“…Maxwell-Eucken assumes that filler particles are homogeneously distributed in the polymer matrix, non-interacting, and roughly spherical. Fewer filler particles would be covered by the polymer and dispersed in the form of isolated islands in the matrix:where V f is the volume fraction of the filler, and λ c , λ f , and λ p is the thermal conductivity of composites, filler, and matrix, respectively 31, 32 . In this paper, the value of λ f and λ p used 6.032 W m −1  K −1 and 0.315 W m −1  K −1 , respectively.…”
Section: Resultsmentioning
confidence: 99%
“…Maxwell-Eucken assumes that filler particles are homogeneously distributed in the polymer matrix, non-interacting, and roughly spherical. Fewer filler particles would be covered by the polymer and dispersed in the form of isolated islands in the matrix:where V f is the volume fraction of the filler, and λ c , λ f , and λ p is the thermal conductivity of composites, filler, and matrix, respectively 31, 32 . In this paper, the value of λ f and λ p used 6.032 W m −1  K −1 and 0.315 W m −1  K −1 , respectively.…”
Section: Resultsmentioning
confidence: 99%
“…By electrospinning technology, the polymer chains are changed from the random arrangement to ideal single crystal nanofibers, a benefit for obtaining an extremely high λ value. In addition, some special structural monomer by chemical synthesis can also be performed to fabricate polymers with high λ value, such as PA, PANI, and PPy [114], mainly depending on conjugated π bond, to realize thermal conduction through electron conduction mechanism. Kurabayashi [115] reported the thermal conductivities and mechanisms of polyvinyl chloride (PVC), polymethyl methacrylate (PMMA), polycarbonate Fig.…”
Section: Fabrication Methods Of Intrinsic Thermally Conductive Polymersmentioning
confidence: 99%
“…Even if Eq. (4) could yield results comparable to the experimental ones, it is not straightforward to calculate TR from the factor α [37]. This is where FE method offers more acceptable results and direct computation of K eff and TR.…”
Section: Theoretical Vs Experimental Resultsmentioning
confidence: 96%