2005
DOI: 10.1016/j.jphotochem.2004.11.013
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The photodegradation of pyrromethene 567 and pyrromethene 597 by pyrromethene 546

Abstract: The photo-destabilizing action of 1,3,5,7,8-pentamethylpyrromethene difluoroborate complex (PM546) on 1,3,5,7,8-pentamethyl-2,6-diethylpyrromethene difluoroborate complex (PM567) and 1,3,5,7,8-pentamethyl-2,6-di-t-butylpyrromethene difluoroborate complex (PM597) has been investigated. Acetonitrile solutions of PM567 and PM597 demonstrated accelerated photodegradation upon the addition of PM546; whereas the photodegradation rate of the corresponding n-hexane solutions remained invariant with respect to PM546 ad… Show more

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Cited by 13 publications
(3 citation statements)
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References 18 publications
(16 reference statements)
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“…This faster rate is most likely caused by an excited state electron energy transfer, as discussed for similar Pyrromethene dyes in Ref. [46]. The electron energy transfer is from the excited state of the acceptor dye to the ground state of the donor dye.…”
Section: Agingmentioning
confidence: 80%
“…This faster rate is most likely caused by an excited state electron energy transfer, as discussed for similar Pyrromethene dyes in Ref. [46]. The electron energy transfer is from the excited state of the acceptor dye to the ground state of the donor dye.…”
Section: Agingmentioning
confidence: 80%
“…4,6,14 We have recently reported the enhanced photodegradation of Pyrromethene 567 and Pyrromethene 597 by Pyrromethene 546 via electron transfer. 28 The photoexcited Pyrromethene 567/597 donates an electron to Pyrromethene 546 initiating photodegradation. In that pyrromethene system a competition exists between dye electron donation and 1 O 2 photooxidation.…”
Section: Singlet Oxygen Quantum Yieldmentioning
confidence: 99%
“…The adhesive was cured after each dispensing step in a nitrogen environment using an LED-based UV curing system (365nm LED head, Aicure UJ35, Panasonic). Curing under nitrogen minimizes any UV-induced degradation of the organic dye by minimizing the concentration of oxygen [34]. The output power of the curing lamp was set to approximately 1.2 W/cm 2 on the surface of the sensor chips, with 15 seconds of curing time for each dispensing step.…”
Section: Passivation Conceptmentioning
confidence: 99%