The kinetics of transient liquid phase (TLP) solidification in Au-Sn layers electroplated on Cu foil was investigated using differential scanning calorimetry (DSC). The solidification reaction takes place between a eutectic liquid of melting point 280 ЊC, which is shown to form in preference to other compositions, and an excess gold-rich layer. The solidification kinetics and the amount of melt formed were measured as a function of foil aging time. It is shown that the well-documented rapid interdiffusion at low temperatures between gold and tin can account for a decrease in the amount of melt produced during heating with age time. An estimate of the effective diffusivity of tin into gold at 295 ЊC has been obtained from measured solidification rates. The effect of copper diffusing through the gold film on the solidification kinetics was also investigated.