1973
DOI: 10.1016/s0040-4020(01)83153-7
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The chemistry of piperidines—I

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1973
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Cited by 10 publications
(1 citation statement)
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“…A few cases of lactone formation in 3-ABNs are known. An attempt to cleave the tosyl group in ethyl Ar-tosyl-9-exo-hydroxy-3-ABN-7-endo-carboxylate (280) way the N-tosyl-7-exo-hydroxy-3-ABN-9-one (284) is shown to exist in equilibrium with the hemiacetal 285.290 The unsaturated 3-ABN derivative 286 when heated with HCHO gives substituted azaadamantanol297 (287).…”
Section: B Reactions Of Carbonyl Groupsmentioning
confidence: 99%
“…A few cases of lactone formation in 3-ABNs are known. An attempt to cleave the tosyl group in ethyl Ar-tosyl-9-exo-hydroxy-3-ABN-7-endo-carboxylate (280) way the N-tosyl-7-exo-hydroxy-3-ABN-9-one (284) is shown to exist in equilibrium with the hemiacetal 285.290 The unsaturated 3-ABN derivative 286 when heated with HCHO gives substituted azaadamantanol297 (287).…”
Section: B Reactions Of Carbonyl Groupsmentioning
confidence: 99%